photochemistry of Fe(III) complexes with salicylic acid derivatives in aqueous solutions

Crystallization, Structure Determination and Reticular Twinning in Iron(III) Salicylate: Fe[(HSal)(Sal)(H2O)2]

“…Another important application of the salicylate ligand is in analytical chemistry. Fe(III) salicylate is a colored complex that can be used for spectrophotometry [4,5]. Spectrophotometric procedures have also been used to establish the stability constants of Fe(III) salicylates [6].…”

The composition and structure of iron(III) complex compounds with salicylic acid in ethanol solution and in the solid thin film state

“…1, curve 2) shows two intense peaks. These spectral peaks in the UV region are assignable to the π→π* and n→π* transitions in salicylate-ion [1,15,16]. As can be seen from Fig.…”

“…Physicochemical studies of salicylates [1][2][3][4][5][6][7] have shown that there exist a large number of ways in which a salicylic acid is coordinated around the central atom. The salicylic acid contains two types of functional groups -a phenolic and carboxyl:…”

“…There is currently much interest in iron(III) salicylate complexes, which has arisen due to the wide scope of applications of these compounds, namely, in biomedicine and environmental monitoring [1][2][3][4]. In recent years complexes of metal salts with salicylic acid have also been intensively investigated for applications in manufacturing oxide film materials by sol-gel method [5][6][7].…”

“…In a great number of works [1][2][3][4]12] studied the complexation between iron(III) salts and salicylic acid in aqueous medium, which is not applicable for the preparation FFS. The most effective solvent for preparing filmforming solutions is ethanol (94-96 wt.…”