“…As a new kind of intelligent material, photochromic materials have important applications in the fields of information encryption, optical information storage, photoelectric materials, optical switches, and optical devices . Electron-deficient viologen derivatives (1,1′-disubstituted 4,4′-bipyridiniums), as good photochromic materials, are widely used in ink-free erasable printing, UV detection, and other fields. − It is because of its electron-deficient nature that it can form charge transfer complexes with electron-rich species and has the redox capability of reversible electron transfer under the stimulation of an external environment, such as light. − Therefore, the combination of viologen and multielectron species can construct more color-changing materials with excellent properties.…”