Thin films of amorphous, diamond-like carbon (DLC) were deposited on crystalline silicon substrates in a capacitively coupled RF-plasma discharge. The investigations concentrated on I-V and C-V measurements, on photoconductivity and on optical transmission between wavelengths of 2 and 50 microns of the heterostructure DLC/Si. The photoconductivity of the heterostructure is investigated for the first time; it depends on the band gap of the film, the thickness and the doping of the substrate. The DLC/Si heterostructure works like a MIS-photoelectric cell.