Photodecarboxylative Benzylation of N‐Alkylphthalimides: A Concise Route to the Aristolactam Skeleton.

Synthesis of Marine-Derived Carbasugar Pericosines

“…The obtained (À)-84 was treated with TFA in MeOH to give (À)-3. A point to note in this synthesis is that both enantiomers were prepared from a single intermediate (81). The realization of this enantiodivergent synthesis in the future will be a useful and powerful method for the synthesis of pericosines.…”

“…5 [79][80][81][82]95]. Interestingly 6 corresponds to the core section of the chlorine-containing natural product (75), which had previously been isolated from two kinds of fungi, and cyathiformine C (76), which are metabolites of basidiomycetous fungi [82,83,96,97].…”