1990
DOI: 10.1016/0009-2614(90)85240-d
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Photodissociation of F2 in crystalline krypton: effect of molecule—lattice prealignment

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Cited by 26 publications
(11 citation statements)
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“…While literature can be found for molecular oxygen in solid hydrogen [31], the question of the preferred crystallographic direction of Cl 2 in solid pH 2 has not yet been investigated and shall be tackled here for the first time with special emphasis on the role of the relaxation of the host particles. Finally, we also note that the chemical reaction dynamics of small molecules embedded in clusters or matrices can be strongly dependent on the nature of the rotational or librational state [32,33]. This has led to suggestions to control reaction yields by manipulation of the rotational degrees of freedom of matrix isolated molecules, e.g., by the non-resonant interaction of their polarisability with short, intense laser pulses [34][35][36].…”
Section: A Accardi and B Schmidtmentioning
confidence: 96%
“…While literature can be found for molecular oxygen in solid hydrogen [31], the question of the preferred crystallographic direction of Cl 2 in solid pH 2 has not yet been investigated and shall be tackled here for the first time with special emphasis on the role of the relaxation of the host particles. Finally, we also note that the chemical reaction dynamics of small molecules embedded in clusters or matrices can be strongly dependent on the nature of the rotational or librational state [32,33]. This has led to suggestions to control reaction yields by manipulation of the rotational degrees of freedom of matrix isolated molecules, e.g., by the non-resonant interaction of their polarisability with short, intense laser pulses [34][35][36].…”
Section: A Accardi and B Schmidtmentioning
confidence: 96%
“…[6][7][8] For lower energies the orientation of F 2 and thus temperature can play a role. 15 The cage exit properties are quite well reproduced by molecular dynamic calculations, 13,16,17 which include the reorientation of the electronic orbital, 17 and by a statistical model. 18 The preparation of the sandwiches with a check of the compactness of the films is given in Sec.…”
Section: Introductionmentioning
confidence: 90%
“…Excitation of an Ar film, exclusively doped with F 2 , in the Ar exciton band ͑11.8 eV͒ leads to one emission band ͓Fig. 3͑a͔͒ at 315 nm, which is characteristic for Ar 2 F. 15,27 The same excitation energy, combined with an Ar film multiply doped with Kr and F 2 , leads to a complete quenching of the Ar 2 F emission and the appearance of two new bands at 345 and 439 nm ͓Fig. 3͑b͔͒, which have been attributed to ArKrF and Kr 2 F trimers.…”
Section: B Kr 2 F Emission Of F Atoms At the Kr/ar Interfacementioning
confidence: 99%
“…Photodissociation of diatomic molecules embedded in condensed matter environments, like rare gas matrices [1][2][3][4][5][6][7][8][9][10][11][12][13][14] or liquids, [15][16][17][18][19][20][21][22][23] has attracted much interest in the last years. Solvation effects have been found to play a major role in the reaction dynamics of these processes.…”
Section: Introductionmentioning
confidence: 99%