As a result of an increasing demand for fabricating metal-free restorations and parallel with the developments in computer-assisted design and computer-assisted manufacturing (CAD-CAM) technology and materials, CAD-CAM high-performance polymers (HPPs) have been introduced as alternative materials to titanium and zirconia. 1-8 HPPs have been increasingly used as a framework material for fixed and removable prostheses and for implant-supported prostheses. These materials have been reported to have favorable thermal and mechanical properties. 1,9-11 Polyaryletherketones (PAEKs) and modified composite resin (MCR) polymers are currently available HPP materials. 6,11-17 Polyetheretherketone (PEEK) and polyetherketoneketone (PEKK) are 2 main groups of the PAEK polymer family that contain an aromatic backbone molecular chain, interconnected by functional ketone and ether groups. 1,2,10-12,16,18-20 PEEK and PEKK are high-temperature semicrystalline thermoplastic polymers with linear chain structures. 10-12,16,18-20 PEEK has been reported to be easily machinable, have low solubility and water absorption, and have high polishability and stability in terms of hardness, rigidity,