This paper presents for the first time the evident experimental confirmation that ΕL2 defect, while being in its metastable configuration, traps under hydrostatic pressure an additional electron, i.e. the acceptor-like ( E L 2 * )°/ -l e v e l e n t e r s t h e e n e r g y g a p u n d e r p r e s s u r e . W e p r o p o s e t h a t i n n -G a A s t h e ΕL2 thermal recovery takes always place via the (ΕL2') state.PACS numbers:71.55.Eq, 78.50.GeOur recent experimental results showed that under pressure of p > 0.3 GPa the metastable configuration of the EL2 defect in GaAs became optically sensitive and a very efficient pure optical recovery process was observed [1]. We suggested that these facts could be related to the acceptor-like level of the metastable EL2 -(EL2*)0/ -, entering the gap under pressure. In this work we present the experimental evidence of the above suggestion. We investigated two n-GaAs samples: #5Β with n300Κ = 1.2 x 1016 cm-3, ΝEL2 = 2.7 x 101 6 c m -3 a n d # 1 5 C w i t h n300κ = 3.2 x 10 16 cm-3 , ΝΕL2 = 1.3 x 1016 cm-3. Clear manifestation of the (EL2*)°/ -level was observed in electrical (conductivity and DLTS) measurements.At temperatures Τ < Τ (where Τ -temperature at which EL2 thermally recovers) and sufficiently high pressure (p > 0.3 GPa) during subsequent optical quenching and optical recovery processes strong persistent changes of the electrical conductivity were observed. This was the consequence of the trapping and releasing of the electrons by EL2 optically transferred between its normal (EL20) and This worlds supported by CPBP 01.05 Program of the Polish Ministry of National Education (129)