Photoelectron emission spectroscopy of inorganic cations in aqueous solution

Photoelectron emission spectroscopy of aqueous solutions

“…Thus, AGe will be equated i Et, and AGr will be calculated from eq 5 for systems for whid AG is known. This will be done 8 The reorganizaticn free energy will be interpreted and correlated with inic solvaticn. 8 The latter is daracterized by the real free energy of solvatian GS defined as 3 ,the free energy change in the process where an icn in field-free space is inserted into a large quantity of solution which Conversely, the reorganization process in the photoelectron emission by Fe 2+…”

Correlation between thermal electron transfer in solution and photoelectron emission

“…We examine in the present paper the relationship between thermal electron transfer and the energetics of photoelectron emission by solutions. This type of optical electron transfer is characterized by a reorganization free energy Rm which can be determined experimentally as was recently shown [7][8][9]. The correlation between the experimental quantities AG* or AG* and R thus obtained provides a very …”

“…By comparing (8) and (12) one verifies that Re = Rx/2 in agreement with [5,10]. This relationship is not rigorous because it corresponds to a simplified treatment of the image force problem.…”

“…The free energy aGm was shown [7][8][9] (6.59) and (6.62) in [2] or eq. (25) in [12], one obtains (rationalized units) respectively; and V is the integration volume.…”

Dielectric dispersion in optical electron transfer in solution

“…This procedure was applied to water [9], inorganic anions [10] and cations [11), and weak acids and bases [12) in aqueous solution. It was found that the exponent p -5/2 gave better fits to linear plots than p -2 for species with Et < 8 eV.…”