Photoelectron spectrum and electronic and steric structure of o-aminothiophenol

Зверев, В. В.; Ashrafullina, L. Kh.; Villem, Ya. Ya.; Villem, N. V.; Shagidullin, R. R.

doi:10.1007/bf00952404

Cited by 2 publications

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“…In case of active solvents it is the M -S bond which is broken first, as it was observed while recrystallization of the (iPrS) 3 PCuBr complex in acetonitrile. Monodentate binding mode via phosphorus was found in crystals after recrystallization, one molecule of acetonitrile being included into the coordination sphere of copper.…”

Section: Resultsmentioning

confidence: 68%

“…There are two features of thiophosphites which indicate that their coordination ability might be significantly different in comparison with oxygen analogues. First, phosphorus donor ability decreases in the series phosphinesphosphites -thiophosphites correspondingly with the ionization potential of the phosphorus lone electron pair [2,3], in trithiophosphites these values for the phosphorus and sulfur atoms being close [3]. Second, the reactivity of phosphites OLGA N. KATAEVA et a!.…”

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confidence: 96%

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Competitive Coordination of Metals by Phosphorus and Sulfur in Complexes with Polydentate Ligands Containing P(III)-S Bonds

Kataeva

Gubaidullin

Литвинов

et al. 1999

Phosphorus, Sulfur, and Silicon and the Related Elements

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A series of complexes of thiophosphites with transition metals has been studied by X-ray single crystal diffraction: CuHal«P(SR) 3 , CuHal'P(SR) 3 «NCMe, CuBr-P(SEt) 2 NEt 2 , CuSCN'P(SR) 3 , CpMn(CO) 2 «P(SR) 3 , ArCr(CO) 2 -P(SR) 3 , with Hal = Cl, Br, I and R = Me, Et, Pr, i-Pr, Bu, Ph. Depending on the metal center, substituents R at sulfur, the conditions of reactions and crystal growth, different coordination modes have been observed: "classical" monodentate binding via phosphorus, unusual bidentate mode with participation of both P and S donor atoms of the ambident P -S system, as well as both monodentate and bidentate modes in one complex.

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Section: Resultsmentioning

confidence: 68%

mentioning

confidence: 96%

Competitive Coordination of Metals by Phosphorus and Sulfur in Complexes with Polydentate Ligands Containing P(III)-S Bonds

Kataeva

Gubaidullin

Литвинов

et al. 1999

Phosphorus, Sulfur, and Silicon and the Related Elements

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“…Conformational analysis has been done on derivatives of both 1,3,2- [314,315] and 1,3,5- [316] derivatives, the former more directly related to the above anticancer species. NPN orbital interactions in 1,3,2-derivatives show consequences for carbanion stability and reactivity [317], hydrolysis rates [318] and ionization energies [319].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Ponikvar

Liebman

2008

Struct Chem

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In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year's articles were briefly summarized and a thermochemical comment written to supplement them. Frequently questions were asked and future research was suggested.Keywords Structural Chemistry Á Thermochemistry Á Thermodynamics Á Enthalpy of formation Á Enthalpy of phase change Á Enthalpy of reaction As practiced disciplines, structural chemistry and thermochemistry are very often unrelated. In this study, these disciplines are linked as relations are explicitly made using the contents of the journal Structural Chemistry (Vol. 18) for the calendar year 2007 as a scaffold for our analysis, for our selected articles in the discipline of structural chemistry. These studies have been reviewed by us, where we give them a thermochemical flavor. While this commentary is most generally written in terms of brief summaries of literature papers involving enthalpies of formation and/or reaction, not uncommonly we raise questions and even suggest possible future research. We are not, however, going to give a thermochemical slant on book reviews, honorary dedications, and obituaries although these works will be cited in our text.As such, this article is a sequel to our earlier related reviews of Structural Chemistry for the calendar years 2000 through 2004 [1-5]. Reviews for 2005 and 2006 are currently being prepared. Issue 1In the first article in the first issue of Structural Chemistry for 2007, Hargittai [6] asserted that while research is currently usually carried out in big groups, the most important ideas, observations and discoveries still belong to individuals who have to bring down dogmas or open entirely new areas in science. This may bring solace to the thermochemical community in which research groups are generally small, and the number of new practitioners sadly few.In the past decade, the crystal engineering of multidimensional arrays and networks containing metal ions has achieved considerable progress because of the increased interest in the potential utility of these compounds as zeolite-like materials [7-11], catalysts [12], or magnetic materials [13][14][15]. The thermochemistry of these species is complicated by their inherent complexity: however, estimation approaches of their key thermochemical quantities are increasingly reliable [16]. In the second article of this issue, by Wang et al. [17], the versatility of malonate dianion as a ligand for the construction of extended networks with different topologies dependent on the coordination geometry of the metal ion was discussed. The synthesis and structure of a novel malonate-bridged copper(II) compound in which copper(II) ions have two different coordination environments in a novel three-dimensional (3D) network was described. Metal malonates have been studied from a

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Photoelectron spectrum and electronic and steric structure of o-aminothiophenol

Cited by 2 publications

References 1 publication

Competitive Coordination of Metals by Phosphorus and Sulfur in Complexes with Polydentate Ligands Containing P(III)-S Bonds

Competitive Coordination of Metals by Phosphorus and Sulfur in Complexes with Polydentate Ligands Containing P(III)-S Bonds

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

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