1996
DOI: 10.1063/1.471904
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Photofragmentation of mass-selected ICl−(CO2)n cluster ions: Solvation effects on the structure and dynamics of the ionic chromophore

Abstract: A 193 nm laser photofragmentation timeofflight mass spectrometric study of CS2 and CS2 clusters

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Cited by 68 publications
(53 citation statements)
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“…Heteronuclear dihalides have not been neglected, however, and they pose some distinct challenges. In 1996, Nadal, Kleiber, and Lineberger 21, 22 measured the photofragmentation products from ICl -and ICl -(CO 2 ) n clusters following excitation at 644 nm ( Figure 1). Excitation of the bare ion to the A′ ( 2 II 1/2 ) state leads exclusively to the formation of iodide (I -) ions and chlorine (Cl) atoms ( Figure 2).…”
Section: Introductionmentioning
confidence: 99%
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“…Heteronuclear dihalides have not been neglected, however, and they pose some distinct challenges. In 1996, Nadal, Kleiber, and Lineberger 21, 22 measured the photofragmentation products from ICl -and ICl -(CO 2 ) n clusters following excitation at 644 nm ( Figure 1). Excitation of the bare ion to the A′ ( 2 II 1/2 ) state leads exclusively to the formation of iodide (I -) ions and chlorine (Cl) atoms ( Figure 2).…”
Section: Introductionmentioning
confidence: 99%
“…Solvent Effects on the Electronic Absorption Spectrum. Nadal, Kleiber, and Lineberger 21, 22 have measured the effect of clustering on the ICl -electronic absorption in the red region of the spectrum. In ICl -(CO 2 ) 4 , the only cluster size studied, they found a small red shift of ∼10 nm in the A′ r X absorption band near 700 nm.…”
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confidence: 99%
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“…44 The electron transfer rate in polar solvents has been recently formulated in terms of the fluctuation of local electrostatic potential produced by solvent molecules. 7 According to the model the ET rate constant kET is expressed as: kET = -~J2(p(eAV# ) (1) where q) is a distribution function of the electrostatic potential energy difference eAV between donor and acceptor sites, and J stands for the transfer integral. The specific value o[ the potential difference in Eq.…”
Section: Introduction***mentioning
confidence: 99%