1982
DOI: 10.1016/s0040-4039(00)87633-9
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Photoinduced anti-markovnikov addition of methanol to alkylindenes

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Cited by 3 publications
(4 citation statements)
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“…The electronic set-up in the intermediate should, therefore, be optimal for an anti-elimination reaction (cf: [22]) with anchimeric assistance of the adjacent diene and uptake of the nucleophile at C (8). Morrisan and coworkers [7] [23] found that irradiation of 1-methylindene (26) in 0 . 2 5~ H,SO,/MeOH leads to the formation of a 4:l mixture of frans-and cis-9 (Scheme 9 ) .…”
Section: Endo -22mentioning
confidence: 99%
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“…The electronic set-up in the intermediate should, therefore, be optimal for an anti-elimination reaction (cf: [22]) with anchimeric assistance of the adjacent diene and uptake of the nucleophile at C (8). Morrisan and coworkers [7] [23] found that irradiation of 1-methylindene (26) in 0 . 2 5~ H,SO,/MeOH leads to the formation of a 4:l mixture of frans-and cis-9 (Scheme 9 ) .…”
Section: Endo -22mentioning
confidence: 99%
“…This reaction should be catalyzable by acids. (23). 2-(3'-Methyl-2'-butenyl)aniline [27] (1.0 g, 6.20 mmol), Me1 (2.4 g, 16.9 mmol), and K2C03 (2.34 g, 16.9 mmol) were stirred in acetone at r. 1466, 1448, 1438, 1418, 1412, 1403.…”
Section: (E)/jz)-2-(2'-butenyl/-nn-dime/hyluni/ine ( ( E ) / ( Z ) -mentioning
confidence: 99%
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