“…-Secondly, brought together, observations concerning 1-bpy and 1-phen indicate that, as far as -interaction is concerned, which has by far the largest contribution to intramolecular electronic communication, geometrical decoupling is rather efficient to produce electronic decoupling, including within closely coupled and compact assemblies. This issue is in line with literature reports concerning other less compact assemblies [1,111,114,115,117,147,[153][154][155][156][157][158][159].…”