Photoinduced grafting polymerization onto the surface with the use of radiation of high-power ultraviolet light-emitting diodes

Третинников, О. Н.; Gorbachev, A. A.; Луценко, Е. В.; Данильчик, А. В.; Shkrabatovskaya, L. V.; Prikhodchenko, L. K.

doi:10.1134/s1560090416030155

Cited by 4 publications

(2 citation statements)

References 16 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…However, for these systems, several reaction conditions need to be previously set; thus, the study often becomes cumbersome. Although there are a lot of studies where the support surface has been modified by using a UV-induced reaction, − there is generally little information about the effect of light power on the reaction performance . Therefore, in this work we researched the effect of the reaction mixture position about light source and the reaction time on the performance of a photograft polymerization.…”

Section: Introductionmentioning

confidence: 99%

“…Although there are a lot of studies where the support surface has been modified by using a UVinduced reaction, 21−24 there is generally little information about the effect of light power on the reaction performance. 25 Therefore, in this work we researched the effect of the reaction mixture position about light source and the reaction time on the performance of a photograft polymerization. The surface of PP films was modified by using a UV-induced graft polymerization of acrylic acid (AA), selected as a reaction model.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Optimization of UV-Induced Graft Polymerization of Acrylic Acid on Polypropylene Films Using CdS as Light Sensor

Stragliotto

Strumia

Gómez

et al. 2018

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Photoconductive cell of CdS was used to optimize the photograft polymerization of acrylic acid (AA) onto polypropylene film surface. Effect of UV-light intensity on the performance of this reaction in the three-dimensional space inside the reactor was researched. A relationship between light intensity measured as conductance and performance of the AA graft reaction was found. In addition, a linear relationship (r 2 = 0.98) between the grafting degree (G) and conductance (G/wt% = (2.2 ± 0.1) 10 4 c − (0.3 ± 0.4)) was determined in the range of 5 to 20% G, where a minimum stabilization time, such as 5 min, was required. Standard deviation of the Gvalue and the conductance decreased when a longer distance between the film and the lamp was used, leading to a more homogeneous surface modification. Therefore, we propose this system as a new method to monitor and predict the performance of UV-induced reactions.

show abstract