Photoluminescence and Electron Spin Resonance of Silicon Dioxide Crystal with Rutile Structure (Stishovite)

Abstract

An electron spin resonance (ESR) and photoluminescence signal is observed in the as grown single crystal of stishovite indicating the presence of defects in the non‐irradiated sample. The photoluminescence of the as received stishovite single crystals exhibits two main bands – a blue at 3 eV and an UV at 4.75 eV. Luminescence is excited in the range of optical transparency of stishovite (below 8.75 eV) and, therefore, is ascribed to defects. A wide range of decay kinetics under a pulsed excitation is observed. For the blue band besides the exponential decay with a time constant of about 18 μs an additional ms component is revealed. For the UV band besides the fast component with a time constant of 1–3 ns a component with a decay in tens μs is obtained. The main components (18 μs and 1–3 ns) possess a typical intra‐center transition intensity thermal quenching. The effect of the additional slow component is related to the presence of OH groups and/or carbon molecular defects modifying the luminescence center. The additional slow components exhibit wave‐like thermal dependences. Photo‐thermally stimulated creation–destruction of the complex comprising host defect and interstitial modifiers explains the slow luminescence wave‐like thermal dependences.

Energy Transport in SiO2 Crystals: Luminescence Excitation Spectra of Stishovite and α-Quartz

“…Another part of the process is recombination. Thus, the effect of increasing the photoluminescence duration up to ms for the blue band and up to tens of microseconds for the UV band was discovered when a single crystal of stishovite was heated even to a high (340 K) temperature [12]. The effect is explained by the formation of a certain complex with an OH group or / and a diamond-like carbon defect upon photo-excitation of the luminescence center.…”

“…The effect is explained by the formation of a certain complex with an OH group or / and a diamond-like carbon defect upon photo-excitation of the luminescence center. The complex is destroyed by heating, providing slow recombination luminescence [12].…”