“…In the recent years, considerable attention has been focused on these materials (glasses), due to their threshold and memory switching effects and the infrared transmission of many of these glasses which make them potential materials of industrial applications in memory devices, fiber optics, guided wave devices and infrared telecommunication systems [1][2][3][4][5][6][7][8][9][10]. When these glasses are irradiated with high energy particles or light, bond breaking and bond rearrangement can take place, which result in the change in local structure of the glassy materials, which leads to changes in the optical constants [11,12] and absorption edge shift [13], which make these materials suitable for the fabrication of the large number of optical devices. Thus, the estimation of the optical parameters of chalcogenide glasses is obviously necessary in order to know the basic mechanism underlying these phenomena, and also to exploit and develop their technological applications.…”