“…Nanowires, typically 1–100 μm long and 1–200 nm wide, are an important class of one‐dimensional nanomaterials and have been extensively studied for a long time; different kinds of nanowires have been prepared, including SiO 2 ,2 ZnO,3 and TiO 2 4. Among these materials, amorphous silica as an important kind of optical candidate material is of great interest because of its convenient synthesis methods, mechanical and thermal stability, chemical inertness, corrosion resistance, and efficient photoluminescence emission 5. It was also found that silica nanowires are suitable to be doped or coated with other functional materials,6 and it has been reported that among the Eu 3+ ‐doped materials, the luminescent quantum efficiency of nanowires was better than that of nanoparticles and bulk powders,7 which extends the applications of Eu 3+ ‐doped silica nanowires in the fields of luminescent devices and functional optoelectronic materials.…”