2005
DOI: 10.1002/pssc.200460250
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Photoluminescence in neutron irradiated fused silica

Abstract: In this work, the effects of neutron irradiations (10 21 n/m 2 and 10 22 n/m 2 doses) on photoluminescence of several fused silica grades with different OH contents are studied. Neutron irradiation induces three emission processes: at 4.2 eV with maximum excitation energy around 4.95 eV and halfwidth of 0.27 eV, at 1.9 eV with excitation around 4.6 eV, and at 2.3 eV with two components (4.6 eV and 3.9 eV) excitation spectra. The emission at 2.3 eV has not been previously reported at room temperature. Dose depe… Show more

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Cited by 12 publications
(6 citation statements)
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“…The origin of this band is still unknown. A band peaked around 2.3 eV (FWHM of about 0.5 eV) has been observed by Martin et al [13] in silica bulk samples irradiated with neutrons at fluences higher than 10 17 n/cm 2 . Since they reported the excitation of this PL, consisting of two bands peaked at 4.6 eV (FWHM of 0.6 eV) and 3.9 eV (FWHM of 0.64 eV), we decided to study its decay by exciting this PL near the maximum of its excitation spectrum, 4.43 eV.…”
Section: Photoluminescencesupporting
confidence: 54%
“…The origin of this band is still unknown. A band peaked around 2.3 eV (FWHM of about 0.5 eV) has been observed by Martin et al [13] in silica bulk samples irradiated with neutrons at fluences higher than 10 17 n/cm 2 . Since they reported the excitation of this PL, consisting of two bands peaked at 4.6 eV (FWHM of 0.6 eV) and 3.9 eV (FWHM of 0.64 eV), we decided to study its decay by exciting this PL near the maximum of its excitation spectrum, 4.43 eV.…”
Section: Photoluminescencesupporting
confidence: 54%
“…Another PL band is observed in the green region with characteristics depending on the radiation nature: we find that it is peaked at 527 nm for 10 17 n/cm 2 + > 2 MGy irradiated sample, whereas it is centered at 515 nm for 10 MGy irradiated sample. We acknowledge that a similar band was observed in [18], [19]; these finding suggest that neutrons induce an intrinsic peculiar defect characterized by this green photoluminescence. The radial distribution of the PL band at 530 nm, reported in Fig.…”
Section: B Spectroscopic Analysissupporting
confidence: 78%
“…We focused this work on the structural changes occurring in these various glasses at such high doses and fluences, as a complete study on the optical changes induced by γ-rays and neutron irradiation has already been done in the same samples [18,19,20,21,22,23]. To highlight the radiation induced mechanisms for both photons and neutrons, we have characterized the glass properties before and after both types of irradiations.…”
Section: Introductionmentioning
confidence: 99%