“…4 (left)), which includes six main Gaussian-type peaks at 366, 396, 428, 450, 468 and 550 nm, denoted as A, B, C, D, E and F, respectively. The 366 nm peak stems from CB → VB direct recombination [20], which is larger than the forbidden gap because TiO 2 is indirect gap semiconductor [5,21], and the peak at 550 nm is ascribed to indirect recombination via the oxygen vacancies [20]. The other peaks should be related to the surface electronic structure and indirect recombination via bulk defects.…”