“…Due to the fact that the Γ-valley energy reduces faster than the one of the L-valley, Ge transforms into a direct band gap semiconductor at ~4.7% uniaxial strain along [100] when the direct transition (black line) decreases below the energy of the indirect recombination (green line). For Ge under biaxial tensile strain or GeSn alloys, the band edges behave similarly with an indirect-to-direct band gap crossover at ~1.6-2.0% strain (El Kurdi et al, 2010;Virgilio et al, 2013;Wen and Bellotti, 2015) or and at a Sn-content of ~9% (Low et al, 2012;Gupta et al, 2013b;Wirths et al, 2015) for a fully relaxed layer.…”