Photoluminescence study on irradiated yttria stabilized zirconia

Halder, Rumu; Sengupta, P.; Sudarsan, V.; Ghosh, Abhijit; Bhukta, Anjan; Sharma, Geeta; Samajdar, I.; Dey, G.K.

doi:10.1016/j.jnucmat.2014.10.007

Cited by 14 publications

(3 citation statements)

References 62 publications

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“…The extrinsic vacancies formed in order to maintain the charge neutrality are mainly oxygen vacancies associated with samarium cation. The origin of luminescence in cubic zirconia is associated with complexes formed by oxygen vacancies in a disordered sub -lattice particularly those involving a cation, either Sm 3+ or Zr 4+ in seven fold coordination [38].…”

Section: Uv-visible Absorption and Energy Band Gap Analysismentioning

confidence: 99%

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Gurushantha¹,

Anantharaju

Sharma³

et al. 2016

Journal of Alloys and Compounds

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Section: Uv-visible Absorption and Energy Band Gap Analysismentioning

confidence: 99%

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Gurushantha¹,

Anantharaju

Sharma³

et al. 2016

Journal of Alloys and Compounds

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“…At higher Pr 3+ concentration, there is a 488 nm emission peak due to the creation of a high number of defects that could possibly act as non-radiative luminescence centers. The emission peaks observed at 420 and 435 nm are attributed to vacancy complexes of the type Zr-O-Pr and Pr-O-Zr [23].…”

Section: Resultsmentioning

confidence: 97%

Effect of Pr doping on structure and luminescence properties of ZrO₂ nanoparticles

Lokesha

Chithambo

Tatumi

et al. 2023

J. Phys. D: Appl. Phys.

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Pr3+ impurity transitions in monoclinic and cubic phases of ZrO2 have been investigated by photoluminescence and thermoluminescence. Zr(1− x)PrxO2(0 ≤ x ≥ 0.015) samples were prepared by the combustion method. Rietveld refined x-ray diffraction results confirm that undoped ZrO2 has a monoclinic structure whereas Pr doped ZrO2 samples are in mixed phase consisting of monoclinic and cubic structures. ZrO2 shows a broad defect-related emission peak centered at 500 nm under an excitation wavelength of 300 nm. A series of Pr3+ -related emissions are observed at 512, 584, 612-640 nm due to 3P0→3H4, 3P1+1I6→3H5, 1D2→3H4 transitions and between 719-740 nm due to 1D2→3H5 transitions when excited with 454 nm. The PL decay lifetime of Zr0.996Pr0.004O2 is 1.55 μs for fixed λex = 300 nm and λem = 612 nm. The thermoluminescence glow curve of Zr0.99Pr0.01O2 shows a prominent peak at 695 K and secondary peaks at 508 K and 570 K which are not observed in undoped ZrO2. TL emission measured at 695 K confirm that Pr3+ replaces Zr4+ in cubic lattice sites of ZrO2. This work shows the relationship between luminescence properties and different structures of ZrO2 and that supports to design of new materials for possible applications.

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“…Thus, the PL properties of YSZ show its electronic band structure and indispensable defects in synthesis of bulk forms. To date, the PL properties of non-doped and rare earth doped YSZ have been reported elsewhere [10][11][12][13][14][15][16], and YSZ is well known as one of the good phosphors, which has various emission wavelengths. However, as far as we are aware, no studies have been reported on the radiation induced luminescence properties of YSZ.…”

Section: Introductionmentioning

confidence: 99%

Scintillation, OSL and TSL properties of yttria stabilized zirconia crystal

Nakauchi

Okada

Yanagida

2016

Journal of Luminescence

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We investigated the scintillation and dosimeter properties of yttria stabilized zirconia (YSZ, Y2O3-ZrO2) crystal. It showed 70-80% in-line transmittance at wavelength longer than 300 nm. Under excitations around the bandgap energy, several intense photoluminescence (PL) emission peaks appeared at 450, 550, 570 and 600 nm, and the PL decay time constants were 5.5 and 20.7 ns. In the X-ray induced scintillation spectrum, an intense emission peak around 450 nm was observed, and the scintillation decay time constants were 14.4 and 169.8 ns. After irradiations with X-rays, thermally stimulated luminescence (TSL) glow peaks appeared at 100, 200 and 450 o C. Also, after X-ray irradiations, optically stimulated luminescence (OSL) was detected around 500 nm with 650 nm stimulation.

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Photoluminescence study on irradiated yttria stabilized zirconia

Cited by 14 publications

References 62 publications

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Effect of Pr doping on structure and luminescence properties of ZrO₂ nanoparticles

Scintillation, OSL and TSL properties of yttria stabilized zirconia crystal

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Photoluminescence study on irradiated yttria stabilized zirconia

Cited by 14 publications

References 62 publications

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Bio-mediated Sm doped nano cubic zirconia: Photoluminescent, Judd–Ofelt analysis, electrochemical impedance spectroscopy and photocatalytic performance

Effect of Pr doping on structure and luminescence properties of ZrO2 nanoparticles

Scintillation, OSL and TSL properties of yttria stabilized zirconia crystal

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Effect of Pr doping on structure and luminescence properties of ZrO₂ nanoparticles