Photolysis of Methyl Iodide in the Presence of Nitric Oxide

Johnston, Timothy; Heicklen, Julian

doi:10.1021/j100882a012

Cited by 26 publications

(8 citation statements)

References 7 publications

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“…14 The data reveal the formation of a salt composed of a guanidinium‐type cation and a triiodide anion. The formation of this salt might proceed through an alkylation of the central N3 atom with subsequent liberation of nitrosyl iodine, which decomposes to give I 2 24. A second methylation would give the cation along with the triiodide anion.…”

Section: Methodsmentioning

confidence: 99%

Covalent Capture of Nitrous Oxide by N‐Heterocyclic Carbenes

et al. 2011

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Section: Methodsmentioning

confidence: 99%

Covalent Capture of Nitrous Oxide by N‐Heterocyclic Carbenes

et al. 2011

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“…Various investigators (Calvert, et al, 1960;Christie, 1958b;Christie, et al, 1965;Johnston and Heicklen, 1966) obtained values between 12 and 87 1./(mole sec) for the second-order rate constant for the dimerization of nitrosomethane at 25°C. Rates of the thermal decomposition of the dimers of nitrosomethane were also measured (Batt, et al, 1960;Christie, et al, 1965).…”

Section: Chsnomentioning

confidence: 99%

Rate and Mechanism of the Partial Oxidation of Acetaldehyde by Parts-per-Million Concentrations of Nitrogen Dioxide

Davis¹,

Corcoran²

1972

Ind. Eng. Chem. Fund.

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The thermal reaction between nitrogen dioxide and acetaldehyde in the gas phase was studied at ambient temperature and atmospheric pressure in a constant-volume batch reactor. Initial partial pressures of nitrogen dioxide varied between 0.01 and 0.03 mm, while the partial pressure of acetaldehyde ranged from 20 to 50 mm. The initial rate of disappearance of nitrogen dioxide was determined to be an order of 1.00 ± 0.03 for nitrogen dioxide and 1.00 ± 0.07 for acetaldehyde. From data for initial rates at 22.0°C, a second-order rate constant of (8.596 ± 0.189) X 1 0~3 l./(mole sec) was obtained at a total pressure of

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“…The speed of the transformation could be accelerated by placing the reaction flask next to a mercury lamp. [24] A second methylation would give the cation along with the triiodide anion. Compound 4 was examined spectroscopically as well as by single-crystal X-ray analysis ( Figure 2).…”

mentioning

confidence: 99%

“…The formation of this salt might proceed through an alkylation of the central N3 atom with subsequent liberation of nitrosyl iodine, which decomposes to give I 2 . [24] A second methylation would give the cation along with the triiodide anion. However, a more detailed study is needed to corroborate this mechanistic hypothesis.…”

mentioning

confidence: 99%