Photolysis of Tricarbonyl(η5-cyclohexadienyl)manganese in Tetrahydrofuran, Reactions with Cumulated Dienes

Kreiter, Cornelius G.; Wachter, Norbert K.; Reiß, Guido J.

doi:10.1002/(sici)1099-0682(199904)1999:4<655::aid-ejic655>3.0.co;2-y

Cited by 7 publications

References 31 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Bitterwolf¹

2005

Encyclopedia of Inorganic Chemistry

View full text Add to dashboard Cite

Photochemistry has evolved into a powerful tool for the highly selective generation of reactive intermediates in inorganic and organometallic chemistry. This review examines the state of the art in the examination of mechanisms of photochemical reactions utilizing techniques such as frozen matrices and fast time‐resolved methods. The application of photochemistry to the preparation of dihydrogen, alkane, and noble gas intermediates is reviewed along with the significance of these intermediates in the understanding of the mechanism of oxidative addition processes. Experiment and theory of charge transfer phenomena are extensively discussed along with the application of these processes to semiconductor and biochemical studies. Applications of photocrystallography to the examination of linkage isomers and very short‐lived excited state species are reviewed. Finally, a number of examples of the application of photochemical reactions, such as the photolysis of Fisher carbene species to generate ketenelike intermediates, to synthesis are discussed. The literature is reviewed to the end of 2003.

show abstract

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Bitterwolf¹

2005

Encyclopedia of Inorganic Chemistry

View full text Add to dashboard Cite

show abstract

Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

Palii

Zagorevskii

2011

Patai's Chemistry of Functional Groups

View full text Add to dashboard Cite

This review (782 references) represents an exhaustive up‐to‐date survey of literature on mass spectrometry and gas‐phase ion chemistry of organomanganese complexes. Fundamental physico‐chemical characteristics of organomanganese ionic species, as well as the gas‐phase reactions resulting in the dissociation or formation of manganese‐carbon bond(s) are examined. Circa 300 examples of ion/molecule reactions characterizing the reactivity of Mn + , positively or negatively charged manganese clusters, as well as neutrals, cations and anions of various Mn‐containing species (including coordinatively unsaturated ones) are summarized. A variety of studies involving tandem mass spectrometry, neutralization‐reionization mass spectrometry, collision‐induced dissociation, multiple‐photon dissociation, IRMPD spectroscopy and theoretical calculations for organomanganese ion structure characterization are discussed. Additionally, analytical applications of mass spectrometric techniques to the characterization of compounds containing a MnC bond are reviewed. These include a number of relatively simple mononuclear complexes, polynuclear clusters, complexes incorporating organometallic units bridged with organic fragment(s), bifunctional compounds containing organometallic and classical Werner‐type coordination sites, fullerenes or planar polyaromatic hydrocarbons with an organomanganese fragment attached to them, manganospiralenes, manganoscorpionates, supramolecular entities, cymantrene‐peptide bioconjugates, etc.

show abstract

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Rose‐Munch

Rose

Eloi

2010

Patai's Chemistry of Functional Groups

View full text Add to dashboard Cite

The tricarbonyl‐chromium and ‐manganese groups are known to easily coordinate arene rings to form η 6 ‐arene complexes. The electrophilic nature of the tricarbonyl metal fragments makes the arene electron‐deficient and renders it susceptible to nucleophilic attack. It is for these reasons that a new trend has emerged, the study of the chemistry of (η 5 ‐cyclohexadienyl)Mn(CO) 3 complexes which are easily obtained by addition of a nucleophile to the arene ring. In the last ten years, the discovery of new methods of functionalization involving Pd cross‐coupling and lithiation reactions has greatly expanded the scope of the (η 5 ‐cyclohexadienyl)Mn(CO) 3 complexes and consequently represents a key step in the development of the arene manganese chemistry since [(η 6 ‐arene)Mn(CO) 3 ] + complexes can be easily obtained by rearomatization of the corresponding (η 5 ‐cyclohexadienyl)Mn derivatives. The present review aims to describe the situation for the synthesis and the reactivity of η 6 ‐arene‐Mn complexes as well as that of η 5 ‐cyclohexadienyl‐Mn complexes to highlight the recent breakthrough in their chemistry. The main reactivities described for η 5 Mn complexes correspond to nucleophilic addition, lithiation/electrophilic quench, lithium/halogen exchange and Pd catalyzed reactions. These types of reactions can be efficiently compared with those well studied in η 6 arenetricarbonylchromium complexes. All these recent developments in the functionalization of η 5 ‐ and η 6 ‐Mn complexes described in this chapter clearly open a revival period for this type of complexes which are starting to emerge as a valuable and versatile class of compounds more environmentally friendly than their Cr analogs.

show abstract

Photolysis of Tricarbonyl(η5-cyclohexadienyl)manganese in Tetrahydrofuran, Reactions with Cumulated Dienes

Cited by 7 publications

References 31 publications

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Contact Info

Product

Resources

About

Photolysis of Tricarbonyl(η5-cyclohexadienyl)manganese in Tetrahydrofuran, Reactions with Cumulated Dienes

Cited by 7 publications

References 31 publications

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Photochemistry of Transition Metal ComplexesBased in part on the article Photochemistry of Transition Metal Complexes by Lisa McElwee‐White which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Mass Spectrometry and Gas‐Phase Ion Chemistry of Organomanganese Complexes

Cationic (η6‐arene)‐ and Neutral (η5‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity

Contact Info

Product

Resources

About

Cationic (η⁶‐arene)‐ and Neutral (η⁵‐cyclohexadienyl)‐tricarbonylmanganese Complexes: Synthesis and Reactivity