Photolytic insertion of carbon monoxide into nitrosyl chloride: formation of nitrosoformyl chloride

Lü, Bo; Jiang, Xin; Zeng, Xiaoqing

doi:10.1039/d2cp02913h

Phys. Chem. Chem. Phys.

2022

DOI: 10.1039/d2cp02913h

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Photolytic insertion of carbon monoxide into nitrosyl chloride: formation of nitrosoformyl chloride

Bo Lü

Xin Jiang

Xiaoqing Zeng

Abstract: Nitrosocarbonyls are exotic intermediates that remain scarcely characterized. By UV photolysis (365 nm) of nitrosyl chloride (ClNO) embedded in solid CO ice at 20 K, the elusive nitrosoformyl chloride (ClC(O)NO)...

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Light induced reactions in cryogenic matrices (highlights 2021–2022)

Fausto,

Nikitin,

Nogueira

2023

Photochemistry

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This chapter surveys research on light induced reactions of organic molecules investigated in cryogenic matrices that has been reported during 2021 and 2022. It highlights studies dealing with conformational changes, tautomerizations and other structural isomerizations induced either by ultraviolet/visible or infrared light, as well as photofragmentation reactions. Emphasis is given to reactive intermediates, including nitrenes, carbenes and radicals. The studies featured in the present review are examples of recent applications of the matrix isolation method, coupled with spectroscopic probing, to these areas of investigation.

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Light induced reactions in cryogenic matrices (highlights 2021–2022)

Fausto,

Nikitin,

Nogueira

2023

Photochemistry

View full text Add to dashboard Cite

show abstract

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Photolytic insertion of carbon monoxide into nitrosyl chloride: formation of nitrosoformyl chloride

Abstract: Nitrosocarbonyls are exotic intermediates that remain scarcely characterized. By UV photolysis (365 nm) of nitrosyl chloride (ClNO) embedded in solid CO ice at 20 K, the elusive nitrosoformyl chloride (ClC(O)NO)...

Cited by 1 publication

References 63 publications

Light induced reactions in cryogenic matrices (highlights 2021–2022)

Light induced reactions in cryogenic matrices (highlights 2021–2022)

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