Photomediated Synthesis of β‐Alkylketones from Cycloalkanes.

Abstract

C-C bond formation O 0282 Photomediated Synthesis of β-Alkylketones from Cycloalkanes. -Conditions which allow successful addition of unactivated cycloalkanes to enones are developed. -(DONDI, D.; CARDARELLI, A. M.; FAGNONI*, M.; ALBINI, A.; Tetrahedron 62 (2006) 23, 5527-5535; Dip. Chim.

Semiconductors in Organic Photosynthesis

“…TBADT has been also used by Albini and coworkers to promote the photocatalytic radical conjugate addition of electron-poor olefins by cycloakanes (Eq. 22) (Dondi et al, 2006) and the acylation of ,-unsaturated nitriles, ketones and esters (Eq. 23) (Esposti et al, 2007), affording the desired products in good yields.…”