Surface and Interface Science 2013
DOI: 10.1002/9783527680535.ch9
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Photon‐Based Methods: 3.4.1 Photon Spectroscopies

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“…At the same time, the band at 2950 cm −1 gained in intensity, assignable to sp 3 -hybridized ν(CH 2 ). This confirms sp 3 hybridization of the C atom and is supported by the implication of di-σ-bonded ethylene 47 in addition to the w(CH 2 ) mode at 1032 cm −1 . It is noteworthy that the stretching vibration mode of CH 2 is very weak on CeO 2 -673K-H in comparison with that on CeO 2 -673K-O, possibly due to its restricted movement caused by H bonding with hydride/OH species (Figure S10)…”
Section: ■ Results and Discussionsupporting
confidence: 68%
“…At the same time, the band at 2950 cm −1 gained in intensity, assignable to sp 3 -hybridized ν(CH 2 ). This confirms sp 3 hybridization of the C atom and is supported by the implication of di-σ-bonded ethylene 47 in addition to the w(CH 2 ) mode at 1032 cm −1 . It is noteworthy that the stretching vibration mode of CH 2 is very weak on CeO 2 -673K-H in comparison with that on CeO 2 -673K-O, possibly due to its restricted movement caused by H bonding with hydride/OH species (Figure S10)…”
Section: ■ Results and Discussionsupporting
confidence: 68%