Cathodoluminescence
(CL) imaging spectroscopy provides two-dimensional
optical excitation images of photonic nanostructures with a deep-subwavelength
spatial resolution. So far, CL imaging was unable to provide a direct
measurement of the excitation and emission probabilities of photonic
nanostructures in a spatially resolved manner. Here, we demonstrate
that by mapping the cathodoluminescence autocorrelation function g(2) together with the CL spectral distribution the excitation
and emission rates can be disentangled at every excitation position.
We use InGaN/GaN quantum wells in GaN nanowires with diameters in
the range 200–500 nm as a model system to test our new g(2) mapping methodology and find characteristic differences
in excitation and emission rates both between wires and within wires.
Strong differences in the average CL intensity between the wires are
the result of differences in the emission efficiencies. At the highest
spatial resolution, intensity variations observed within wires are
the result of excitation rates that vary with the nanoscale geometry
of the structures. The fact that strong spatial variations observed
in the CL intensity are not only uniquely linked to variations in
emission efficiency but also linked to excitation efficiency has profound
implications for the interpretation of the CL data for nanostructured
geometries in general.