The optical properties of photonic structures made with more than two materials are very interesting for optical filtering and lighting applications. Herein, we compared the transmission properties of one--dimensional photonic crystals made with three, four and five materials, showing that, with a photonic crystal made of t different materials, the band gap splits in t--1 bands. The same optical thickness for the different materials layers results in split photonic band gaps with the same intensity. Photonic crystals with more than two materials result in a simple structure that could be used for multi--feature optical filters, or that could provide feedback for multi--emission distributed feedback lasers. Furthermore, we analyzed the transmission properties of ternary and quaternary random photonic structures. These materials could very interesting for light trapping in photovoltaic devices. Introduction Photonic crystals provide the possibility to manipulate light: a periodic modulation of the refractive index results in a forbidden energy gap that excludes the existence of optical modes within a certain range of wavelengths [1--6]. In the last twenty years, several methods have been established to fabricate photonic crystals at diverse length scales. as layer--by--layer stacking techniques using microfabrication tools [7][8][9], electrochemical etching [10,11], laser--beam--scanning chemical vapour deposition [12], and holographic lithography [13,14]. The periodicity of dielectric constant can be in one, two and three dimensions [15--18]. In the case of one--dimensional structures, well established and low--cost fabrication technologies, as spin coating or co--extrusion, can be employed [15,19]. Recently, these materials are extensively studied since they find application in several fields, including photonics for low threshold laser action, high bending angle waveguide, super--prism effect, sensors and optical switches [20--25]. The calculation of the optical properties can be analytically performed with several theoretical methods, as a fully--vectorial algorithm to compute the definite--frequency eigenstates of Maxwell's equations, developed by Johnson and Joannopoulos [26], or the transfer matrix method [27]. In particular, the transfer matrix approach also allows to study the properties of photonic quasicrystals [28] and disordered photonic structures [29]. In the case on one--dimensional disordered, it is possible to employ also a finite element method [30]. Owing to their interesting features, the study of one--dimensional photonic crystals (1DPCs) made with more than two materials is recently increased. For example, ternary photonic crystals have been theoretically investigated [31,32]. With these crystals it is usually shown omnidirectional reflectance; an interesting case is a ternary Fibonacci sequence in which one of the three materials is a superconductor [33]. In 2012 quaternary photonic crystals have been proposed [34]. In this work, we compared the transmission properties of one--dimen...