2002
DOI: 10.1063/1.1431698
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Photonic crystals of core-shell colloidal particles

Abstract: We report on the fabrication and optical transmission studies of thin three-dimensional (3D) photonic crystals of high-dielectric ZnS-core and low-dielectric SiO 2 -shell colloidal particles.These samples were fabricated using a vertical controlled drying method. The spectral position and width of a stopgap depend on the core-to-shell ratio, in a manner consistent with numerical calculations. Both experiments and calculations show that the relative L-stopgap width in the case of high-index core low-index shell… Show more

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Cited by 146 publications
(102 citation statements)
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“…The main disadvantage of this method is that it is hard to avoid the appearance of considerable amounts of lattice defects during the fabrication, which may destroy the photonic band gap [52]. Recently, fabrication of ordered arrays of ice [53], titania [54], zinc sulfide [55,56], gold core-shell particles [57], and other 3D photonic crystals were reported. In this thesis we will exclusively use artificial opals fabricated by self-assembly.…”
Section: Fabrication Methodsmentioning
confidence: 99%
“…The main disadvantage of this method is that it is hard to avoid the appearance of considerable amounts of lattice defects during the fabrication, which may destroy the photonic band gap [52]. Recently, fabrication of ordered arrays of ice [53], titania [54], zinc sulfide [55,56], gold core-shell particles [57], and other 3D photonic crystals were reported. In this thesis we will exclusively use artificial opals fabricated by self-assembly.…”
Section: Fabrication Methodsmentioning
confidence: 99%
“…Current experimental colloidal techniques allow one to design a variety of multi-structured beads having a plurality of concentric shells with the core radius from cca 1 nm till 1 µm and controlled shell thicknesses. For instance, metal (Au, Ag, Pt) and dielectric (ZnS) beads can be coated in a controlled way by a silica shell [23,24,25,26,27], and a dielectric (silica, Au 2 S) bead can be coated by gold or some other noble metal [22,28,29,30,31,32]. One can subsequently etched away silica core of a silica-core metal-shell bead and obtain a hollow metallic nanoshell.…”
Section: Introductionmentioning
confidence: 99%
“…Controlling the difference of the refractive index of the shell and the core and also the arrangement of the balls on a regular three-dimensional lattice, one can obtain colloidal crystals with full photonic band gap in the visible [4,5].…”
Section: Introductionmentioning
confidence: 99%