Photophysical and redox properties of new donor–acceptor–donor (DAD) compounds containing benzothiadiazole (A) and dimethyldihydroacridine (D) units: a combined experimental and theoretical study

Abstract

Four donor-acceptor-donor compounds consisting of 9,9-dimethyl-9,10-dihydroacridine donors differently linked to benzothiadiazole acceptor were designed using DFT calculations and synthesized, namely 4,7-bis(4-(9,9-dimethyl-9,10-dihydroacridine)phenyl)benzo[c][1,2,5]thiadiazole (1), 4,7-Bis(2,5-dimethyl-4-(9,9-dimethyl-9,10-dihydroacridine)phenyl)benzo[c][1,2,5]thiadiazole (2), 4,7-Bis(3,5-di(9,9-dimethyl-9,10-dihydroacridine)phenyl)benzo[c][1,2,5]thiadiazole (3), 4-(3,5-di(9,9-dimethyl-9,10-dihydroacridine)phenyl)-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (4). As predicted...