Photophysical properties and photonic applications of porphyrin-based MOFs

Mehrzad Sajjadinezhad, Seyed; Boivin, Léo; Bouarab, Kamal; Harvey, Pierre D.

doi:10.1016/j.ccr.2024.215794

Cited by 14 publications

(1 citation statement)

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“…It is an opportune moment to offer a review on porphyrin-based MOFs for photo(electro)catalytic CO 2 reduction. Up to now, although there have been many inspiring reviews on porphyrin-based MOFs for various applications, 66–72 a comprehensive review focusing on porphyrin-based MOFs for photo(electro)catalytic CO 2 reduction is inexistent. In this review, the synthetic approaches of porphyrin-based MOFs and the basic principle of CO 2 reduction are firstly described.…”

Section: Introductionmentioning

confidence: 99%

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Ding,

Li,

Chen

et al. 2024

Energy Environ. Sci.

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Section: Introductionmentioning

confidence: 99%

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Ding,

Li,

Chen

et al. 2024

Energy Environ. Sci.

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Metal‐Organic Cages: Synthetic Strategies and Photocatalytic Application

Liu,

Huang,

Qin

et al. 2024

ChemCatChem

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Metal‐organic cages (MOCs) are a class of compounds formed through the coordination of metal ions with organic ligands to create well‐defined and cage‐like structure. These unique structures offer versatile environments for catalyzing a wide range of chemical reactions. The catalytic capabilities of MOCs are significantly influenced by the nature of the metal ions, functional ligands, and the cage structure. Notably, the confined spaces within MOCs can lead to enhanced reaction efficiencies, particularly in processes such as light‐induced hydrogen generation and the photocatalytic reduction of CO2. Furthermore, MOCs show great potential in photo‐organic synthesis due to the cage structure which provide a confined environment, and allow for encapsulating organic molecules, making them useful for improving the selectivity and efficiency of catalytic process. This review reports the development of MOCs for photocatalysis, focusing on the structural design and regulation strategy to build functional MOCs for photocatalytic hydrogen production, CO2 reduction, organic transformation. Insights into the photocatalysis are discussed including the challenges and further research direction in MOC‐based photocatalysis.

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Elevating Nonlinear Optical Response Through D‐Electron Modulation in Metal–Organic Frameworks

Lu,

Huo,

et al. 2024

Chemistry A European J

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Electronic structure and excited state behavior is of pronounced influence on regulation of nonlinear optical (NLO) response. Herein, a serials of transition metal ions bearing different d‐electron numbers were in situ coordinated within porphyrinic metal‐organic frameworks (MOFs), creating NLO‐responsive M‐metal (metal = Fe, Co, Ni, Cu, and Zn) frameworks. It demonstrated that the NLO properties can be optimized with the increased occupancy of the d‐shell, which enhances the degree of delocalization. Specifically, the full‐filled (d10) electron configuration of Zn2+ stabilizes the electronic structure, combination with π‐π* local excitation character of M‐Zn, promoting charge transfer process and resulting in outstanding NLO properties. Moreover, parameters related to the nonlinear process (β, n2, Imχ(3), Reχ(3) and χ(3)) of M‐Zn are calculated to be higher than those of other materials, consistent with theoretical calculations. This work paves the way for NLO modulation based on electronic analysis and provides a promising approach for constructing high‐performance NLO materials.

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Photophysical properties and photonic applications of porphyrin-based MOFs

Cited by 14 publications

References 150 publications

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Metal‐Organic Cages: Synthetic Strategies and Photocatalytic Application

Elevating Nonlinear Optical Response Through D‐Electron Modulation in Metal–Organic Frameworks

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Photophysical properties and photonic applications of porphyrin-based MOFs

Cited by 14 publications

References 150 publications

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO2 reduction

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO2 reduction

Metal‐Organic Cages: Synthetic Strategies and Photocatalytic Application

Elevating Nonlinear Optical Response Through D‐Electron Modulation in Metal–Organic Frameworks

Contact Info

Product

Resources

About

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction

Porphyrin-based metal–organic frameworks for photo(electro)catalytic CO₂ reduction