1983
DOI: 10.1021/cr00057a001
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Photopolymerization of diolefin crystals

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1985
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Cited by 293 publications
(140 citation statements)
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“…The basic concepts of topochemistry 1) initially developed for interpreting the [2 + 2] photocycloaddition of monoolefinic chromophores in the crystalline state have been successfully extended to crystalline compounds bearing two independent reactive groups, thus opening the route to solid state step-growth photopolymerization proceeding under strict control of the crystal lattice 2) . The original photodimerization reaction exhibited by various crystalline forms of cinnamic acid 3,4) , which is still a subject of academic interest 5) , has been adapted some four decades ago for obtaining organic photo-imaging system based on photocross-linkable polymers 6) .…”
Section: Introductionmentioning
confidence: 99%
“…The basic concepts of topochemistry 1) initially developed for interpreting the [2 + 2] photocycloaddition of monoolefinic chromophores in the crystalline state have been successfully extended to crystalline compounds bearing two independent reactive groups, thus opening the route to solid state step-growth photopolymerization proceeding under strict control of the crystal lattice 2) . The original photodimerization reaction exhibited by various crystalline forms of cinnamic acid 3,4) , which is still a subject of academic interest 5) , has been adapted some four decades ago for obtaining organic photo-imaging system based on photocross-linkable polymers 6) .…”
Section: Introductionmentioning
confidence: 99%
“…Consequently, after years of research, only a limited number of systems including dieth-ylenes, diacetylenes, and coordination complexes of nickel were reported that undergo lattice-controlled polymerization beyond dimers and trimers. [11][12][13][14][15][16][17] Heterogeneous solid-gas or solid-liquid reactions are even less stereospecific, since the reactant crystal is already damaged at the early stages of the chemical transformation.…”
mentioning
confidence: 99%
“…It agreed with a step-growth mechanism, as was expected for the photo-polymerization of this compound. 33 In the desorption profiles for the sample shown in Fig. 11b, the desorption temperatures for the dimer, tetramer, and hexamer were similar to each other, and were all lower than those for the trimer and pentamer.…”
Section: Methodsmentioning
confidence: 63%