The magnetoresistance, electric and photoconductivity of polymeric films based on polyvinylbutyral doped with compounds with intramolecular charge transfer (CICT) and containing nanoparticles Fe 2 O 3 have been investigated. The photoconductivity of such polymeric compositions is governed by photogeneration of non-equilibrium charge carriers from excited with light CICT molecules and by their transport inside and between the particles. Revealing of inner photoeffect in investigated nanocomposite are of interest for development of new mediums with photomagnetic properties.Introduction Films of polymeric compositions (PC) with inorganic nanoparticles (NP) are of interest due to their possible using in molecular electronics (see, e.g. [1]). As such their electric and photoconducting properties are of great importance. These properties are determined by the concentration and dimensions of the NP and are quite different, compared to the same bulk materials. A decrease of the NP dimensions is accompanied by a hypsochromic shift of the edge of optical absorption band. Therefore, in such PC, photoeffects within visible and near IR parts of spectrum are small [2]. Sensitization of PC by dyes or related compounds [3, 4] is one possibility aimed at extending the spectral range of their photosensitivity. However, the efficiency of the inner photoeffect attributed to light absorption by sensitizer and photogeneration of charge carriers, depends on possibilities of electronic transitions between the sensitizer molecules and the NP. The present paper is aimed at investigation the electric and photoconductivity properties of PC films based on polyvinylbutyral (PVB) doped with organic compounds with intramolecular charge transfer (CICT) [5] and containing NP Fe 2 O 3 . PVB possesses good film-forming features. The films without special doping appear among dielectrics and are transparent for visible light. CICT are quite well dissoluble in PC, have wide and intensive bands of electronic absorption in visible and near IR ranges of light spectrum and are used as sensitizers of photoconductivity in recording mediums based on organic photosemiconductors [6]. That is why, one can suppose that CICT can serve as centers of charge photogeneration in PC with NP as well.