1998
DOI: 10.1002/(sici)1097-4601(1998)30:10<711::aid-kin3>3.0.co;2-y
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Photoreduction of IrCl62? complex in alcohol solutions and its reaction with hydroxyalkyl radicals

Abstract: The photochemistry of complex in simple alcohols have been studied using 2ϪIrCl 6 laser-flash photolysis. Single electron transfer from the solvent molecule to the light-excited complex has been shown to be the primary photochemical process. Quantum yields of the photoreduction of complex and the rate constants of its reaction with hydroxyalkyl 2ϪIrCl 6 radicals were determined at Deviations of the rate constants from Debye-Smo-200-330 K. luchowski equation for diffusion-controlled reactions are discussed.

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Cited by 13 publications
(48 citation statements)
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“…It is interesting to study the phototransformations of the IrCl 6 2-complex for the determination of primary mechanisms in photochemistry of transition metal halide complexes. The IrCl 6 2-complex has an exclusively stable coordination sphere and is stable in aqueous solutions and in organic solvents.…”
supporting
confidence: 81%
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“…It is interesting to study the phototransformations of the IrCl 6 2-complex for the determination of primary mechanisms in photochemistry of transition metal halide complexes. The IrCl 6 2-complex has an exclusively stable coordination sphere and is stable in aqueous solutions and in organic solvents.…”
supporting
confidence: 81%
“…Laser flash photolysis (308 nm) was applied to study photochemistry of the IrCl 6 2-complex in aqueous solutions in the presence of the Br -anions. The formation of the Br 2…”
mentioning
confidence: 99%
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