“…The presence of surface and interface states give rise to electrical potential profiles at the surface, which are located within the gap region, between the CB and VB. The surface states may arise due to either surface contamination, or imperfections at the surface, or due to dangling bonds associated with incomplete covalent bonding [35,36,37]. The surface breaks the translational symmetry of the perfect crystal, thus leading to the appearance of the known Tamm levels [38,39].…”