The temperature dependence of ultraviolet photorefraction of iron-doped ␣-LiIO 3 crystals is studied. Within the temperature range of 120-220 K diffraction efficiency and two-wave mixing gain increase dramatically with decreasing temperature and become as high as 36% and 3.1 cm Ϫ1 , respectively, below 120 K. The results of holographic recording experiments are compared with measurements of the dielectric susceptance, electric conductivity, and absorption of acoustic waves to establish a relationship between the change in photorefraction and the temperature dependence of the dielectric and ultrasonic behavior. Iron doping of ␣-LiIO 3 enhances the photorefraction considerably. ͓S0163-1829͑98͒05615-X͔