“…The first one is the GeODC (II) defect reaction with hydrogen under UV absorption leading to a hydrogen containing species like H-bearing species. Then, under two-photon absorption [26], these species transform into GeE 0 releasing hydrogen. This part of the mechanism leads to several features: a dramatic increase in the GeE 0 concentration and thus a dramatic increase in the refractive index at the beginning of the exposure.…”
Section: Tentative Mechanisms Of Species Transformation During Uv Expmentioning
confidence: 99%
“…Starting from a comprehensive survey of the literature, we have suggested in Refs. [26,27] a mechanism that is summarized by the following equations: The first mechanism (at the top of the group) is composed by two successive reactions. The first one is the GeODC (II) defect reaction with hydrogen under UV absorption leading to a hydrogen containing species like H-bearing species.…”
Section: Tentative Mechanisms Of Species Transformation During Uv Expmentioning
“…The first one is the GeODC (II) defect reaction with hydrogen under UV absorption leading to a hydrogen containing species like H-bearing species. Then, under two-photon absorption [26], these species transform into GeE 0 releasing hydrogen. This part of the mechanism leads to several features: a dramatic increase in the GeE 0 concentration and thus a dramatic increase in the refractive index at the beginning of the exposure.…”
Section: Tentative Mechanisms Of Species Transformation During Uv Expmentioning
confidence: 99%
“…Starting from a comprehensive survey of the literature, we have suggested in Refs. [26,27] a mechanism that is summarized by the following equations: The first mechanism (at the top of the group) is composed by two successive reactions. The first one is the GeODC (II) defect reaction with hydrogen under UV absorption leading to a hydrogen containing species like H-bearing species.…”
Section: Tentative Mechanisms Of Species Transformation During Uv Expmentioning
“…To this purpose, the fibers were exposed through a phase mask (Lasiris; pitch = 1057 nm; diffraction power efficiency in the −1, +1 and 0 orders = 34%, 34% and 1% respectively) to a cw laser emitting at 244 nm. All the exposures were carried out at a mean power density ≈35 W/cm 2 . In this paper we will investigate two series of FBG.…”
Section: Fiber Bragg Gratings (Fbg) Writing Methods and Pre-treatmentsmentioning
confidence: 99%
“…They are usually reflectivity and sometimes Bragg wavelength and Bragg bandwidth. The relation between these quantities and the refractive index changes (noted RIC below) along the grating are explained in Reference [2,3]. Let us recall only the important features.…”
Section: Fbg Writing and Accelerated Ageing Experimentsmentioning
confidence: 99%
“…We have also to remark that beyond the assumption of a limiting reaction, Δn(z, t w , T w ) arises from several physical phenomena directly proportional to each other's [2,3]: creation of species with a polarizability different from the non-irradiated matter polarizability, some re-organization of the matter (e.g., glass density changes) and stress redistribution. All these phenomena can thus be reduced to only one species that we will call B in such a way that the question of stability of the RIC restricts only to the stability of B.…”
Section: The Lifetime Prediction Theory: the Master Curve Formalism Amentioning
This paper is dedicated to the lifetime prediction of Type I Fiber Bragg gratings (FBG) and to problems that happen when stabilization (also called passivation) conditions or the industrial conditioning procedure depart from ageing ones (e.g., presence of hydrogen during the passivation process). For the first time, a reliable procedure to certify the predicted lifetime based on a "restricted" master curve built on real components (i.e., passivated FBG) is presented. It is worth noting that both procedures (master curve built on non-passivated or on passivated components) are based on the same model (demarcation energy approximation and the existence of a master curve) fed with ageing data (reflectivity decay vs. time and temperature). If the Master Curve (MC) build on passivated components can be derived from the original one, we can certify the lifetime prediction in a reliable manner.
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