“…In a heterogenous planar surface, the surface coverage y(T, m) can be obtained considering the integral equation. [38][39][40] The idea is to build a total isotherm by adding local homogeneous isotherms y k (e, m) weighted by different energy distributions f k (e), thus,…”
Section: Integral Equation For Nanostructuresmentioning
confidence: 99%
“…In a heterogenous planar surface, the surface coverage θ ( T , μ ) can be obtained considering the integral equation. 38–40 The idea is to build a total isotherm by adding local homogeneous isotherms θ k ( ε , μ ) weighted by different energy distributions f k ( ε ), thus,Here, k runs over the set of physically allowed adsorption sites corresponding to different heterogenous regions. These regions can be combinations of planar surfaces with different coordination numbers or even can include nanostructures.…”
Section: Integral Equation For Nanostructuresmentioning
Two theoretical approximations, the theoretical approach of energy levels and the extension of the modified mean field approach (TAEL and MMFA, respectively) are applied to the study of surface decoration...
“…In a heterogenous planar surface, the surface coverage y(T, m) can be obtained considering the integral equation. [38][39][40] The idea is to build a total isotherm by adding local homogeneous isotherms y k (e, m) weighted by different energy distributions f k (e), thus,…”
Section: Integral Equation For Nanostructuresmentioning
confidence: 99%
“…In a heterogenous planar surface, the surface coverage θ ( T , μ ) can be obtained considering the integral equation. 38–40 The idea is to build a total isotherm by adding local homogeneous isotherms θ k ( ε , μ ) weighted by different energy distributions f k ( ε ), thus,Here, k runs over the set of physically allowed adsorption sites corresponding to different heterogenous regions. These regions can be combinations of planar surfaces with different coordination numbers or even can include nanostructures.…”
Section: Integral Equation For Nanostructuresmentioning
Two theoretical approximations, the theoretical approach of energy levels and the extension of the modified mean field approach (TAEL and MMFA, respectively) are applied to the study of surface decoration...
“…The theoretical model presented here is based on the integral equation usually used in studies associated with heterogeneous surfaces. 29–31 Here, the total isotherm θ ( E ) of a heterogeneous surface can be obtained by integrating local homogenous isotherms multiplied by a frequency distribution over a range of energies. Specifically,where θ L ( E , μ ) is the local isotherm, associated with adsorption sites with energy E , at potential μ and T temperature, and f ( E ) correspond to its distribution.…”
Section: The Theoretical Approach To Energy Levels (Tael) and The Mod...mentioning
confidence: 99%
“…To obtain the total isotherm for adsorption on heterogeneous surfaces, the integral equation 28–31 can be considered. For this it is necessary to know the local isotherms and the energy distribution function.…”
The main objective of this work is to present a new theoretical basis to describe the surface deposition on a modified surface electrode. The surface is modified by the irreversible...
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