The Paper investigates the properties and use of fly ash produced from technologies developed to reduce environmental impact/improve efficiency of the coal-fired power generation process. These include, NOx reduction, co-combustion, supercritical steam technology and oxy-fuel combustion. The nine samples examined were characterized physically, chemically and in terms of their reactivity. Tests were also carried out for consistence and compressive strength of concrete. Comparisons were made with (i) a selection of reference fly ashes, (ii) the requirements of EN 450-1 and (iii) fly ash studies from the 1980s and 1990s. The results indicate that for some processes, fly ash tended to be coarser and of higher loss-on-ignition (co-combustion and incombustion NOx reduction), while for others lower carbon contents were found (supercritical steam), or there was little obvious effect. Fly ash chemistry was slightly affected in some cases, but mainly as expected for the coal being used. There was general agreement between water requirement and activity index with fly ash fineness. Similar effects were noted with concrete in terms of superplasticizing admixture dose for a target slump and compressive strength. The behaviour of the materials was similar to that from the earlier studies and suggests suitability for use in concrete construction.