Electrification and lightning are simulated for a small continental multicell storm. The results are consistent with observations and thus provide additional understanding of the charging processes and evolution of this storm. The first six observed lightning flashes, all negative cloud-to-ground (CG) flashes, indicated at least an inverted dipole charge structure (negative charge above positive). Negative CG flashes should be energetically favorable only when the negative charge region contains appreciably more charge than the lower positive region. The simulations support the hypothesis that the negative charge is enhanced by noninductive charge separation higher in the storm that also causes development of an upper positive charge region, resulting in a "bottom-heavy" tripole charge structure. The two-moment microphysics scheme used for this study can predict mass mixing ratio and number concentration of cloud droplets, rain, ice crystals, snow, graupel, and hail. (Hail was not needed for the present study.) Essential details of the scheme are presented. Bulk particle density of graupel and hail can also be predicted, which increases diversity in fall speeds. The prediction of hydrometeor number concentration is critical for effective charge separation at higher temperatures (−5 < T < −15) in the mixed-phase region, where ice crystals are produced by rime fracturing (Hallett-Mossop process) and by splintering of freezing drops.