We present an updated version of POLARIS, a well established code designated for dust polarisation and line radiative transfer (RT) in arbitrary astrophysical environments. We extend the already available capabilities with a synchrotron feature for polarised emission. Here, we combine state-ofthe-art solutions of the synchrotron RT coefficients with numerical methods for solving the complete system of equations of the RT problem, including Faraday rotation (FR) as well as Faraday conversion (FC). We validate the code against Galactic and extragalactic observations by performing a statistical analysis of synthetic all-sky synchrotron maps for positions within the galaxy and for extragalactic observations. For these test scenarios we apply a model of the Milky Way based on sophisticated magneto-hydrodynamic (MHD) simulations and population-synthesis post-processing techniques.We explore different parameters for modeling the distribution of free electrons and for a turbulent magnetic field component. We find that a strongly fluctuating field is necessary for simulating synthetic synchrotron observations on small scales, we argue that Faraday rotation alone can account for the depolarisation of the synchrotron signal, and we discuss the importance of the observer position within the Milky Way. Altogether, we conclude that POLARIS is a highly reliable tool for predicting synchrotron emission and polarisation, including Faraday rotation in a realistic galactic context. It can thus contribute to better understand the results from current and future observational missions.