Physical Properties of HCFO-1233zd(E)

Hulse, Ryan; Basu, R. S.; Singh, Rajiv R. P.; Thomas, Raymond H. P.

doi:10.1021/je300776s

Cited by 94 publications

(91 citation statements)

References 10 publications

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“…The good reproduction of both the vapor pressure curve and the vapor− liquid coexistence curve (VLCC) of HCFO-1233zd(E) results in an excellent estimate of the critical temperature, critical density, and the normal boiling point, as they deviate by less than 1% from the reported experimental values. 1,7,23 Though the simulation results yield a higher critical temperature then the experimental T c value, which than results in an overestimation of the critical pressure.…”

Section: Journal Of Chemical and Engineering Datamentioning

confidence: 80%

“…The GEMC simulation results for vapor pressure, saturated densities, and heats of vaporization of the vapor−liquid equilibria of the trans-and cis-isomers of 1-chloro-3,3,3-trifluoropropene are summarized in Tables 3 and 4, respectively. Figures 2 and 3 show molecular simulation results for the vapor pressure and saturated densities of the trans compound HCFO-1233zd(E) in comparison with experimental data by Hulse et al 7 and Tanaka et al, 22 and with calculations by the latest equation of state by Mondejar et al 23 As the LJ parameters for the chlorine atoms were fine-tuned to reproduce …”

Section: Resultsmentioning

confidence: 96%

“…Experimental data for the HCFO compound R-1233zd(E) in literature only comprise vapor pressure, saturated liquid densities, and liquid viscosities. 7 Studies on the performance of HFO-1336mzz(Z) as a working fluid are based on data from DuPont, 5 which are not available in open literature.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Molecular Simulation Studies on the Vapor–Liquid Equilibria of the cis- and trans-HCFO-1233zd and the cis- and trans-HFO-1336mzz

Raabe

2015

J. Chem. Eng. Data

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Hydrofluoroolefins (HFO) are considered as the fourth generation of working fluids as they exhibit a low Global Warming Potential, though at the moment, only a few members of the HFO family are commercialized. For most HFO compounds, experimental data for their thermophysical properties are rare, which hampers the exploration of their performance in technical applications. In our earlier work [Raabe, G.; Maginn, E. −5751], we have introduced a transferable force field for fluoropropenes, which enables reliable predictions of their thermophysical properties by molecular simulations. In this work, we apply the force field model for simulation studies on the VLE of the hexafluorobutenes cis-and trans-HFO-1336mzz. We additionally present an extension of the force field to the chlorinated compounds cis-and trans-HCFO1233zd, and provide molecular simulation results for the VLE properties of both isomers. As both trans-1233zd and cis-1336mzz are discussed as working fluids for low grade Organic Rankine Cycles (ORC), we also compare their predicted thermophysical properties with those of the widely used ORC-working fluid R-245fa.

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Section: Journal Of Chemical and Engineering Datamentioning

confidence: 80%

Section: Resultsmentioning

confidence: 96%

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Molecular Simulation Studies on the Vapor–Liquid Equilibria of the cis- and trans-HCFO-1233zd and the cis- and trans-HFO-1336mzz

Raabe

2015

J. Chem. Eng. Data

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“…We have recently studied two condensable gases with a low global warming potential (GWP) of <6 that have virtually zero ozone depletion potential [22][23][24][25][26][27]. One is trans-1-chloro-3,3,3 -trifluoropropene (CTFP) [22][23][24][25] which has similar properties to PFP such as vapor pressure of 0.13 MPa as shown in Table 1.…”

Section: Introductionmentioning

confidence: 99%

“…One is trans-1-chloro-3,3,3 -trifluoropropene (CTFP) [22][23][24][25] which has similar properties to PFP such as vapor pressure of 0.13 MPa as shown in Table 1. The other is trans-1,3,3,3-tetrafluoropropene (TFP) [26,27] which has a higher saturated vapor pressure of 0.5 MPa in comparison with that of PFP.…”

Section: Introductionmentioning

confidence: 99%

Ultraviolet Nanoimprint Lithography in the Mixture of Condensable Gases with Different Vapor Pressures

Suzuki

Youn

Hiroshima

2016

J. Photopol. Sci. Technol.

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UV nanoimprint lithography (UV-NIL) in condensable gases such as pentafluoropropane (PFP) has been recognized as one of the most promising methods to realize bubble-defect-free UV-NIL with low demolding forces when compared with that in ambient air and He. We have recently studied two condensable gases [trans-1-chloro-3,3,3-trifluoropropene (CTFP) and trans-1,3,3,3-tetrafluoropropene (TFP)] with different vapor pressures and low global warming potentials (GWP) of <6. However, the resulting lithographic pattern quality in UV-NIL remains unclear using CTFP and TFP. In this work, the surface roughness of patterns fabricated using UV-NIL in the CTFP and TFP gases was investigated. In UV-NIL in a CTFP/TFP atmosphere, with an increase in the TFP fraction, the surface roughness decreased. It was also found that the linewidth of tens of nanometer size patterns can be linearly controlled by adjusting the CTFP/TFP fraction; for 70-nm-wide line patterns, the linewidth adjusting ratio was approximately 14%.

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Permeability of Single‐Layer‐Free‐Standing Meshes at Varying Capillary Pressure via a Novel Method

Shattique

Giglio

Dede³

et al. 2023

Adv Materials Inter

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The permeability of mesh wicks is important for various applications, including two‐phase heat transfer. However, the understanding of the permeability of single‐layer, free‐standing mesh wicks, with liquid–gas interfaces on both sides, is limited. A novel and simpler method is presented to determine the permeability of a free‐standing wick and apply it to a representative mesh. This method involves modifying the capillary pressure via elevation and simultaneously measuring the permeability to determine the permeability‐capillary pressure relationship. When applied to a copper mesh with plain weave having undergone surface cleaning, the permeability is found to decrease as capillary pressure for deionized water increases. A dimensional analysis is presented to generalize this data for other mesh sizes with similar weaves and fluids. The behavior of mesh in application is modeled, based on the integration of Darcy's law with an analytic function fit to measured data, and parametric studies are conducted to investigate the superficial velocity of liquids through the mesh under varying driving pressures, transport lengths, and liquid viscosity, based on the obtained capillary pressure–permeability relationship. This study provides valuable insights into the transport properties of mesh wicks, with potential applications in fields such as electronics cooling, electrochemical devices, and fluid purification technologies.

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Physical Properties of HCFO-1233zd(E)

Cited by 94 publications

References 10 publications

Molecular Simulation Studies on the Vapor–Liquid Equilibria of the cis- and trans-HCFO-1233zd and the cis- and trans-HFO-1336mzz

Molecular Simulation Studies on the Vapor–Liquid Equilibria of the cis- and trans-HCFO-1233zd and the cis- and trans-HFO-1336mzz

Ultraviolet Nanoimprint Lithography in the Mixture of Condensable Gases with Different Vapor Pressures

Permeability of Single‐Layer‐Free‐Standing Meshes at Varying Capillary Pressure via a Novel Method

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