2017
DOI: 10.1002/polb.24303
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Physically cross‐linked networks of POSS‐capped poly(acrylate amide)s: Synthesis, morphologies, and shape memory behavior

Abstract: In this work, we synthesized a novel organic–inorganic semitelechelic polymer from polyhedral oligomeric silsesquioxane (POSS) and poly(acrylate amide) (PAA) via reversible addition‐fragmentation chain transfer (RAFT) polymerization. The organic–inorganic semitelechelic polymers have been characterized by means of nuclear magnetic resonance spectroscopy, thermal gravimetric analysis, and dynamic mechanical thermal analysis. It was found that capping POSS groups to the single ends of PAA chains caused a series … Show more

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Cited by 33 publications
(19 citation statements)
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“…IC-POSS derivative 4a 27 and CC-POSS derivatives 7a, 33 7b, 34 and 8a 35 were prepared by following the literatures. Chlorodimethylsilane, chloro(ethyl)dimethylsilane, chlorodimethylvinylsilane, chlorodimethylphenylsilane, vinylcyclohexane, and octaphenyl-POSS (8b) were purchased from Tokyo Chemical Industry Co. (TCI) (Tokyo, Japan).…”
Section: Methodsmentioning
confidence: 99%
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“…IC-POSS derivative 4a 27 and CC-POSS derivatives 7a, 33 7b, 34 and 8a 35 were prepared by following the literatures. Chlorodimethylsilane, chloro(ethyl)dimethylsilane, chlorodimethylvinylsilane, chlorodimethylphenylsilane, vinylcyclohexane, and octaphenyl-POSS (8b) were purchased from Tokyo Chemical Industry Co. (TCI) (Tokyo, Japan).…”
Section: Methodsmentioning
confidence: 99%
“…Trisilanoleheptaisobutyl-POSS (1), trisilanole-heptaphenyl-POSS (2), and trisilanole-heptacyclohexyl-POSS (3) were purchased from Hybrid Plastics Inc., (Hattiesburg, Mississippi, US). IC-POSS derivative 4a 27 and CC-POSS derivatives 7a, 33 7b, 34 and 8a 35 were prepared by following the literatures. 13 C-(100 MHz), and 29 Si-(80 MHz) nuclear magnetic resonance (NMR) spectra were recorded on a Bruker DPX-400 spectrometer (Bruker Biospin GmbH, Rheinstetten, Germany).…”
Section: Methodsmentioning
confidence: 99%
“…Later, a series of POSS‐capped PAAs with variable lengths have been obtained via RAFT polymerization of acrylate in the presence of POSS‐CTA. These POSS‐capped PAAs exhibited clear microphase separation behavior and displayed typical shape‐memory properties due to the combination of POSS–POSS interactions and intermolecular hydrogen‐bonding interactions …”
Section: Synthetic Strategy For Poss‐hybrid Polymers With Well‐definementioning
confidence: 99%
“…These POSS-capped PAAs exhibited clear microphase separation behavior and displayed typical shape-memory properties due to the combination of POSS-POSS interactions and intermolecular hydrogen-bonding interactions. [25] Macromol. Rapid Commun.…”
Section: Structure Of Poss-hybrid Polymers Using Poss Raft Agentsmentioning
confidence: 99%
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