Physicochemical and Thermal Properties of Acrylated Palm Olein as a Promising Biopolymer

Tajau, Rida; Rohani, Rosiah; Salleh, Mek Zah

doi:10.1007/s10924-020-01797-6

Cited by 10 publications

(15 citation statements)

References 46 publications

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“…However, the acrylation process with acrylic acid is still the same for both raw materials. As shown in Table 4, the applied molar ratio of epoxidized palm oil (EPO) to acrylic acid ranged from 1 : 1.5 to 1 : 2.6 with the reaction temperature of 80-120 °C as well [40,41,[48][49][50]. Kosheela et al found that a synthesis at molar ratio of 1 : 1.5, 120 °C, and 2 hours produced the highest conversion rate at 90.69% for palm olein [41].…”

Section: Acrylation Of Epoxidized Palmmentioning

confidence: 99%

Acrylated Biopolymers Derived via Epoxidation and Subsequent Acrylation of Vegetable Oils

Parthiban

Thian

et al. 2022

International Journal of Polymer Science

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Chemically modified vegetable oils have become commercially attractive nowadays because they can be utilized as specialized components for the production of bioplasticizers and biopolymers due to their characteristics as being inexpensive, nontoxic, biodegradable, and renewable products. Due to the presence of unsaturation sites in the vegetable oils, they can be chemically modified and transformed into polymeric monomers such as acrylated epoxidized vegetable oils through well-known processes like epoxidation and acrylation processes. Acrylated epoxidized vegetable oil is a biopolymer that has a multitude of applications and is used mainly as a coating material for plastic, paper, and wood. There is an enormous demand for this biopolymer, and the market growth prospects are huge in some regions of the world. However, there are some challenges in the synthesis of acrylated epoxidized vegetable oils in achieving the performance of similar acrylated polymer derived from petroleum sources. In this paper, the chemical structure, properties, and chemical modifications of different types of vegetable oils were reviewed where the emphasis was given on epoxidation and its subsequent acrylation processes. This paper also highlights four types of epoxidation and their subsequent acrylation processes involving five different vegetable oils.

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Section: Acrylation Of Epoxidized Palmmentioning

confidence: 99%

Acrylated Biopolymers Derived via Epoxidation and Subsequent Acrylation of Vegetable Oils

Parthiban

Thian

et al. 2022

International Journal of Polymer Science

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“…Plant-based materials such as starch are preferred as food packaging film due to their homogeneous matrices [ 45 ]. However, in recent times, plant oils such as acylated palm olein (APO), acylated jatropha oil (AEJO), and acrylated epoxidized palm oil (AEPO) have been used and modified to exhibit high yield and better performance, such as UV-curable and high-hardness surface coatings [ 46 ]. Figure 7 depicts the chemical structures and condition of modified jatropha oil and acrylated epoxidized palm oil.…”

Section: Zno Nps In Surface Coatings and Filmsmentioning

confidence: 99%

Green Approaches, Potentials, and Applications of Zinc Oxide Nanoparticles in Surface Coatings and Films

Rohani

Dzulkharnien

Harun

et al. 2022

Bioinorganic Chemistry and Applications

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Interest in the use of zinc oxide nanoparticles (ZnO NPs) in surface coatings and films has increased as its incorporation can significantly improve the mechanical and antimicrobial properties of coatings and film solutions. In an effort to produce green or eco-friendly products, the potential use of ZnO NPs biosynthesized from natural resources to replace conventional petroleum-derived polymers has been investigated. This review provides an insight into the growing trend of incorporating ZnO NPs into synthetic or semi-synthetic or bio-based polymeric materials via different synthesis methods as well as its characteristics and potential applications in surface coatings and films. The antimicrobial potential of ZnO NPs to inhibit the growth of various types of microorganisms as well as its use in surface coatings or films to impart antimicrobial activities that prevent the spread of microorganisms, especially the COVID-19 virus, was also discussed.

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“…The products were reacted with polyethylene glycol dimethacrylate, and the results indicated that the materials were suitable for drug delivery applications [ 42 ]. The acrylation of a palm oil derivative was also reported, which resulted in a branched polymer bearing biodegradable functional groups [ 43 ]. A one-step acrylation procedure was applied to palm, olive, peanut, rapeseed, corn, canola, and grapeseed oils, and the products were separately mixed with polyurethane acrylate, trimethylolpropane triacrylate, and a photoinitiator to prepare ultraviolet-curable films [ 44 ].…”

Section: Branched and Crosslinked Polymers Based On Pristine Or Chemically Modified Triglyceridesmentioning

confidence: 99%

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

et al. 2021

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This paper provides an overview of the recent progress in research and development dealing with polymers derived from plant oils. It highlights the widening interest in novel approaches to the synthesis, characterization, and properties of these materials from renewable resources and emphasizes their growing impact on sustainable macromolecular science and technology. The monomers used include unmodified triglycerides, their fatty acids or the corresponding esters, and chemically modified triglycerides and fatty acid esters. Comonomers include styrene, divinylbenzene, acrylics, furan derivatives, epoxides, etc. The synthetic pathways adopted for the preparation of these materials are very varied, going from traditional free radical and cationic polymerizations to polycondensation reactions, as well as metatheses and Diels–Alder syntheses. In addition to this general appraisal, the specific topic of the use of tung oil as a source of original polymers, copolymers, and (nano)composites is discussed in greater detail in terms of mechanisms, structures, properties, and possible applications.

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Physicochemical and Thermal Properties of Acrylated Palm Olein as a Promising Biopolymer

Cited by 10 publications

References 46 publications

Acrylated Biopolymers Derived via Epoxidation and Subsequent Acrylation of Vegetable Oils

Acrylated Biopolymers Derived via Epoxidation and Subsequent Acrylation of Vegetable Oils

Green Approaches, Potentials, and Applications of Zinc Oxide Nanoparticles in Surface Coatings and Films

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

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