Physicochemical properties of aqueous solutions of dimethyl- and diethylsulfones

Markaryan, Sh. A.; Aznauryan, Mikayel; Kazoyan, E. A.

doi:10.1134/s0036024411120211

Cited by 11 publications

(4 citation statements)

References 14 publications

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“…The initial volume of the system was chosen to reflect the experimental density of heavy water 54 combined with the apparent molar volume of MSM at the simulated concentration. 55 The simulations of pure D 2 O employing the same protocol were published previously. 20 The system was initially equilibrated for 20 ps with a time step of 0.5 fs in the NVT ensemble using massive Nose− Hoover chain thermostatting.…”

Section: ■ Materials and Methodsmentioning

confidence: 99%

“…In order to compare directly to the FTIR spectra of HDO/H 2 O, all water hydrogen atoms were given the mass of deuterium, i.e., we effectively simulate our solute in D 2 O. The initial volume of the system was chosen to reflect the experimental density of heavy water combined with the apparent molar volume of MSM at the simulated concentration . The simulations of pure D 2 O employing the same protocol were published previously …”

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

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Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature

Panuszko,

Śmiechowski,

Pieloszczyk

et al. 2024

J. Phys. Chem. B

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Section: ■ Materials and Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

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Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature

Panuszko,

Śmiechowski,

Pieloszczyk

et al. 2024

J. Phys. Chem. B

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“…In vitro studies indicate that DMSO 2 can protect cartilage [ 38 ], and it possibly normalizes hypoxia-driven alterations to cellular metabolism [ 39 ]. DMSO 2 has a low viscosity [ 40 ] that affects printing accuracy and high surface tension [ 41 ] which can improve hydrophilicity then can increase cell attractive property as a composite material in the biomaterial matrix [ 42 ].…”

Section: Introductionmentioning

confidence: 99%

PCL and DMSO2 Composites for Bio-Scaffold Materials

et al. 2023

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Polycaprolactone (PCL) has been one of the most popular biomaterials in tissue engineering due to its relatively low melting temperature, excellent thermal stability, and cost-effectiveness. However, its low cell attraction, low elastic modulus, and long-term degradation time have limited its application in a wide range of scaffold studies. Dimethyl sulfone (DMSO2) is a stable and non-hazardous organosulfur compound with low viscosity and high surface tension. PCL and DMSO2 composites may overcome the limitations of PCL as a biomaterial and tailor the properties of biocomposites. In this study, PCL and DMSO2 composites were investigated as a new bio-scaffold material to increase hydrophilicity and mechanical properties and tailor degradation properties in vitro. PCL and DMSO2 were physically mixed with 10, 20, and 30 wt% of DMSO2 to evaluate thermal, hydrophilicity, mechanical, and degradation properties of the composites. The water contact angle of the composites for hydrophilicity decreased by 15.5% compared to pure PCL. The experimental results showed that the mechanical and degradation properties of PCL and DMSO2 were better than those of pure PCL, and the properties can be tuned by regulating DMSO2 concentration in the PCL matrix. The elastic modulus of the composite with 30 wt% of DMSO2 showed 532 MPa, and its degradation time was 18 times faster than that of PCL.

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Surface tension of the binary liquid mixture of water and dimethyl sulfone

Wohlfarth¹

2016

Surface Tension of Pure Liquids and Binary Liquid Mixtures

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Physicochemical properties of aqueous solutions of dimethyl- and diethylsulfones

Cited by 11 publications

References 14 publications

Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature

Weakly Hydrated Solute of Mixed Hydrophobic–Hydrophilic Nature

PCL and DMSO2 Composites for Bio-Scaffold Materials

Surface tension of the binary liquid mixture of water and dimethyl sulfone

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