Physicochemical Properties of Sb, Sn, Zn, and Sb–Sn System

Gancarz, Tomasz; Gąsior, W.; Henein, H.

doi:10.1007/s10765-013-1407-1

Cited by 55 publications

(48 citation statements)

References 39 publications

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“…These properties were only determined for pure liquid constituents: Al, Li, and Zn. They were reported for Al and Zn metals by many authors, e.g., Keene [21] and Gancarz et al [22,23] etc. Data for liquid lithium are more scarce than for Al and Zn elements and were taken from.…”

Section: Introductionmentioning

confidence: 74%

“…Calibration procedure was in detail described elsewhere. [22,25] The crucible used in these experiments had the same dimensions as the one used in our previous work. [22,32] The results presented in this work were measured in the temperature range from 773 K to 973 K (500°C to 700°C) with 50 K temperature step, and the mass of the measured alloys was between 0.5 and 0.7 kg.…”

Section: A Draining Crucible Methods (Dc): Density Surface Tension mentioning

confidence: 99%

“…[20][21][22] i.e. g i , c i , V i , (i = A, B) are viscosity, activity coefficient, and atomic volume of pure components of alloy, respectively.…”

Section: Diffusivitymentioning

confidence: 99%

“…Fig. 3-Temperature dependence of the measured surface tension of liquid Li-Zn alloys, i.e., triangle-pure Zn, [22] diamond-9 at. pct Li, circles-22 at.…”

Section: Thermodynamic Properties Of Liquid Al-li and Li-zn Alloysmentioning

confidence: 99%

“…In this work, the experimental data of surface tension of pure elements, i.e., Al from, [23] Li from [21] and Zn from [22] are used to compute this property for studied alloys. They have been taken as Fig.…”

Section: Surface Properties: Surface Concentration and Surface Tensionmentioning

confidence: 99%

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Bulk and Surface Properties of Liquid Al-Li and Li-Zn Alloys

Trybula

Gancarz

Gąsior

et al. 2014

Metall Mater Trans A

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Physicochemical properties like density, surface tension, and viscosity of liquid binary Al-Li and Li-Zn alloys have been measured using draining crucible method. The experimentally measured surface-tension values have been compared to theoretical results based either on the Butler model or the compound formation model assuming the existence of the most favored A 1 B 2 and A 2 B 3 clusters. Several models for viscosity calculation have been also applied and discussed in confrontation with measured data. Finally, the clustering effects in the liquid Al-Li and Li-Zn alloys have been examined using two microscopic functions, i.e., the concentration fluctuation function in the long-wavelength limit and the Warren-Cowley short-range order parameter.

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Section: Introductionmentioning

confidence: 74%

Section: A Draining Crucible Methods (Dc): Density Surface Tension mentioning

confidence: 99%

“…[20][21][22] i.e. g i , c i , V i , (i = A, B) are viscosity, activity coefficient, and atomic volume of pure components of alloy, respectively.…”

Section: Diffusivitymentioning

confidence: 99%

“…Fig. 3-Temperature dependence of the measured surface tension of liquid Li-Zn alloys, i.e., triangle-pure Zn, [22] diamond-9 at. pct Li, circles-22 at.…”

Section: Thermodynamic Properties Of Liquid Al-li and Li-zn Alloysmentioning

confidence: 99%

Section: Surface Properties: Surface Concentration and Surface Tensionmentioning

confidence: 99%

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Bulk and Surface Properties of Liquid Al-Li and Li-Zn Alloys

Trybula

Gancarz

Gąsior

et al. 2014

Metall Mater Trans A

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Electrochemical Fixation of Carbon Dioxide in Molten Salts on Liquid Zinc Cathode to Zinc@Graphitic Carbon Spheres for Enhanced Energy Storage

Xiao

Weng

et al. 2020

Advanced Energy Materials

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to epoxides is realized in ionic liquids by Sun and co-workers. [14,15] Fixation and utilization of CO 2 is also elaborately explored via designing the metal-CO 2 batteries by Ding and co-workers. [16] Fixation of CO 2 into functional carbonaceous materials by capture and electrochemical reduction of CO 2 in molten salts has many advantages. [6,17-19] CO 2 shows a high solubility in molten salts, guaranteeing a highflux uptake rate for a direct and deep removal of CO 2 from atmosphere and industrial flue gas. [6] The wide electrochemical window of molten salt electrolytes promises a high current efficiency of the electrochemical reduction of CO 2 in molten salts. [6,20-24] The high-temperature environment of inorganic molten salts brings about enhanced mass transfer and facilitated reaction kinetics, enabling an appealing conversion rate of CO 2 free of any precious catalysts. [6,14,15] Molten salts possess a high heat capacity, which means the heat required by the molten salt fixation of CO 2 can be supplied by solar-thermal systems. [17] The decomposition voltage of CO 2-capture-generated CO 3 2− in molten salts is lower than 2.0 V (1.3 V for Li 2 CO 3 , 1.6 V for Na 2 CO 3 , and 1.8 V for K 2 CO 3 at 500 °C), therefore the electricity for the conversion of CO 2 in molten salts can be supplied by solar photovoltaic systems. [17] Finally, oxygen in CO 2 can simultaneously be released as anodic O 2 , which is of prime implications on future colony on Mars. [6] One of the major challenges for the electrochemical fixation of CO 2 in molten salts is the insufficient functionality of the deposited carbon on cathode. [6] Amorphous and disordered carbon is commonly obtained by electrochemical conversion of CO 2 in molten salts, which contradicts with the demands of application devices for carbonaceous materials with high graphitization degree. [6] For example, aluminum-ion (Al-ion) battery (AIB) possesses the merits of low cost, high volumetric capacity, and high safety. Many cathode materials are reported for Al-ion batteries, including carbon-based materials, metal sulfides, and V 2 O 5. [25-27] For carbon-based materials, the carbon with higher graphitization degree commonly possesses better performance for reversible Al storage. [26,27] In this regard, pioneering works were conducted by Lu and coworkers. [7,28-33] In their strategy, a highly porous 3D graphene foam is used as the cathode for rechargeable Al-ion batteries,

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A Short History of Fusible Metals and Alloys – Towards Room Temperature Liquid Metals

et al. 2022

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Liquid metals are a class of materials with a millennia-long history, albeit until 200 years ago, mostly centered on mercurybased applications. The knowledge of mercury's toxicity and the discovery of it's bioaccumulation and biomagnification in the late 20 th century resulted in phasing out mercury for copious application. Lead-based, bismuth-based, and sodiumbased technology has partially replaced mercury, but due to toxicity or reactivity issues, replacements for lead and sodium are sought. The discovery of indium and, especially, gallium has allowed for the third generation of alloys with a melting point close to room temperature. This review gives a comprehensive overview of the technological developments of fusible and liquid metals, i. e., metals and alloys with melting points below ca. 250 °C, from the early days to current research and industrial application. Special emphasis is focused on important steppingstones and recent developments of gallium-based alloys as well as how they could be used for future applications.

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Physicochemical Properties of Sb, Sn, Zn, and Sb–Sn System

Cited by 55 publications

References 39 publications

Bulk and Surface Properties of Liquid Al-Li and Li-Zn Alloys

Bulk and Surface Properties of Liquid Al-Li and Li-Zn Alloys

Electrochemical Fixation of Carbon Dioxide in Molten Salts on Liquid Zinc Cathode to Zinc@Graphitic Carbon Spheres for Enhanced Energy Storage

A Short History of Fusible Metals and Alloys – Towards Room Temperature Liquid Metals

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