Brazilian sugarcane spirits were analyzed to elucidate similarities and dissimilarities by principal component analysis. Nine aldehydes, six alcohols, and six metal cations were identified and quantified. Isobutanol (LD 202.9 mg L À1 ), butiraldehyde (0.08-0.5 mg L À1 ), ethanol (39-47% v=v), and copper (371-6068 mg L À1 ) showed marked similarities, but the concentration levels of n-butanol (1.6-7.3 mg L À1 ), sec-butanol (LD 89 mg L À1 ), formaldehyde (0.1-0.74 mg L À1 ), valeraldehyde (0.04-0.31 mg L À1 ), iron (8.6-139.1 mg L À1 ), and magnesium (LD 1149 mg L À1 ) exhibited differences from samples.