Molecular
dynamics simulations were conducted to systematically
investigate how to maintain and enhance nanofilm pure evaporation
on nanopillar surfaces. First, the dynamics of the evaporation meniscus
and the onset and evolution of nanobubbles on nanopillar surfaces
were characterized. The meniscus can be pinned at the top surface
of the nanopillars during evaporation for perfectly wetting fluid.
The curvature of the meniscus close to nanopillars varies dramatically.
Nanobubbles do not originate from the solid surface, where there is
an ultrathin nonevaporation film due to strong solid–fluid
interaction, but originate and evolve from the corner of nanopillars,
where there is a quick increase in potential energy of the fluid.
Second, according to a parametric study, the smaller pitch between
nanopillars (P) and larger diameter of nanopillars
(D) are found to enhance evaporation but also raise
the possibility of boiling, whereas the smaller height of nanopillars
(H) is found to enhance evaporation and suppress
boiling. Finally, it is revealed that the nanofilm thickness should
be maintained beyond a threshold, which is 20 Å in this work,
to avoid the suppression effect of disjoining pressure on evaporation.
Moreover, it is revealed that whether the evaporative heat transfer
is enhanced on the nanopillar surface compared with the smooth surface
is also affected by the nanofilm thickness. The value of nanofilm
thickness should be determined by the competition between the suppression
effect on evaporation due to the decrease in the volume of supplied
fluid and the existence of capillary pressure and the enhancement
effect on evaporation due to the increase in the heating area. Our
work serves as the guidelines to achieve stable and efficient nanofilm
pure evaporative heat transfer on nanopillar surfaces.