Physikalisch-Chemische Tabellen

Landolt, Hans; Börnstein, Richard

doi:10.1007/978-3-662-25187-4

Cited by 59 publications

(7 citation statements)

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“…. Similarly, there are several well‐established compilations of measured thermodynamic properties and general materials physical chemistry data . However, many existing experimental data repositories are still either too small or too heterogeneous (e.g., different experimental conditions or measurement techniques) for high quality ML models.…”

Section: Data Collectionmentioning

confidence: 99%

A Critical Review of Machine Learning of Energy Materials

Chen

Zuo

et al. 2020

Advanced Energy Materials

422

281

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Machine learning (ML) is rapidly revolutionizing many fields and is starting to change landscapes for physics and chemistry. With its ability to solve complex tasks autonomously, ML is being exploited as a radically new way to help find material correlations, understand materials chemistry, and accelerate the discovery of materials. Here, an in‐depth review of the application of ML to energy materials, including rechargeable alkali‐ion batteries, photovoltaics, catalysts, thermoelectrics, piezoelectrics, and superconductors, is presented. A conceptual framework is first provided for ML in materials science, with a broad overview of different ML techniques as well as best practices. This is followed by a critical discussion of how ML is applied in energy materials. This review is concluded with the perspectives on major challenges and opportunities in this exciting field.

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Section: Data Collectionmentioning

confidence: 99%

A Critical Review of Machine Learning of Energy Materials

Chen

Zuo

et al. 2020

Advanced Energy Materials

422

281

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“…(Harwell) for financial support of this work and to the Department of Scientific and Industrial Research for a maintenance grant held by one of them (K.E.J.). Manuscript received Nov. 16, 1960; revised manuscript received June 28, 1961. This paper was prepared for delivery before the Houston Meeting, Oct. 9-13, 1960.…”

Section: Acknowledgmentmentioning

confidence: 99%

Impedance Phenomena in Molten Salts

Hills¹,

Johnson

1961

J. Electrochem. Soc.

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Impedances have been measured of polarized platinum micro-electrodes in the molten salt systems, LiC1-KC1 at 400~ NaNO~-KNO. at 270~ NaBr-A1Br8 at 225~ and PbCL at 530~ Frequency dispersion of both the observed resistance and capacitance was evident in all cases, but apparent double layer capacities obtained by extrapolation to infinite frequency are in reasonable accord with some previously reported data. They are of magnitudes consistent with a simple Helmholtz model although the anodic values tend to be high, perhaps because of specific adsorption. Some measurements of faradaic impedance have also been made, but these were less successful and the exchange current for the Pt/Pt ~ system is high.Metal~melt interfaces are met with in four connections:(i) undergoing steady cathodic electrolysis either as part of an electroanalytical study or as part of an electrowinning process;(ii) at equilibrium in a melt which may or may not contain a significant concentration of the metal ions, e.g., at the internal surface of a metal vessel containing molten salts;(iii) approximately at equilibrium but subject to a small applied voltage changing periodically with time; and (iv) undergoing steady anodic electrolysis where in many cases the metal dissolves smoothly to form ions of its lowest stable valence state.In each case, the composition of the metal-melt interface and the degree of reactivity of the metal should be explicable in terms of the kinetic parameters (particularly exchange currents) of the various feasible electrode reactions. The structure of the melt in contact with the metal is an important related property of such systems, and some conclusions with regard to this may be drawn from values of double layer capacities at metal-melt interfaces.Until recently, only the a-c impedance method has been applied to the measurement of exchange currents and double layer capacities in melts. Double layer capacities of 15-20 ~F cm -~ were observed at carbon electrodes in cryolite-alumina melts (1), and impedance measurements at carbon electrodes in halide melts were interpreted in terms of a slow heterogeneous anode reaction such as C1 + C1 -* C12 (2).Randles and White (3) found that the capacitypotential curves for mercury in molten alkali nitrates, perchlorates, and bisulfates were shallow parabolas with minimum values of ,~20 #F cm -~. In the case of nitrates, a very high concentration of water increased the capacity and produced some semblance of the "hump" found in the curves for aqueous solutions. The rate constant for the discharge of Ni ~ from nitrates was obtained by a straightforward application of the faradaic impedance theory.Hill (4) measured the impedance of Ag in dilute solutions of AgNO3 in molten LiNO3-NaNO~-KNO~, of Ag in solutions of AgC1 in LiC1-KC1, of W in LiC1-KC1 and W in solutions of TiCL and TiCI~ in LiC1-KC1. In all cases the residual capacity and resistance of the solvent were markedly frequency dependent, the double layer capacities obtained by extrapolation to infinite frequency being 300, 500, ...

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“…Among the comparative ionic conductances of the univalent metallic ions, together with the ammonium ion which has similar behavior, we note certain relations. The figures below are taken from Landolt (5) and refer to ionic conductances at 18°C.…”

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confidence: 99%

The Selective Absorption of Potassium by Animal Cells

Mitchell

Wilson

Stanton

1921

Journal of General Physiology

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1. Frog muscles perfused with Ringer solution in which potassium chloride has been replaced by an equivalent amount of rubidium or cesium chloride take up rubidium or cesium and incorporate them into the tissue substance in such form as to be retained during a subsequent perfusion with potassium-free Ringer solution, provided the muscles contract during the first perfusion. Retention of rubidium or cesium by a resting muscle does not occur. 2. Rats on synthetic diets, adequate in all respects except that potassium was replaced by an equivalent amount of rubidium or cesium, died after a period varying from 10 to 17 days with characteristic symptoms including tetanic spasms. Muscle, heart, liver, kidney, spleen, and lung tissues were then found to contain significant amounts of rubidium or cesium. The concentration of these metals in the muscle amounted, in some cases, as shown by a spectroscopic estimation, to about half the concentration of potassium normally found in mammallian muscle. 3. The results are regarded as tending to confirm the theory that the peculiarities in the physiological effects of potassium, including the facility with which it is "selected" by living cells in preference to sodium, are related to the electronic structure of the potassium ion as compared with that of similar ions. The possible relationship of the comparative migration velocity, a function of the electronic structure, to physiological effects is suggested.

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Physikalisch-Chemische Tabellen

Cited by 59 publications

References 0 publications

A Critical Review of Machine Learning of Energy Materials

A Critical Review of Machine Learning of Energy Materials

Impedance Phenomena in Molten Salts

The Selective Absorption of Potassium by Animal Cells

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