Piezoelectric and nonpiezoelectric films of polyvinylidene fluoride (PVDF) have been treated in a microwave nitrogen and hydrogen plasma. Plasma parameters, e.g. ratio between N 2 and H 2 , plasma power, gas flow rate, and the distance between the sample and the plasma have been varied in order to establish the treatment parameters that constitute a good compromise between an optimum functionalization and a minimum degradation. Under this treatment, the surface properties of PVDF have been modified in a controlled manner, allowing its metallization, necessary in a wide range of applications, without significantly changing its bulk properties.
IntroductionSurface modification, especially metallization, of fluoropolymers is of a particular interest, as these polymeric substrates are one of the most important families of engineering polymers, well known for their physical and chemical inertness [1]. Fluoropolymers are characterized by a small surface energy, which does not allow an adequate adhesion with a metal layer. This is why activation of polymer surfaces prior to metallization is absolutely necessary [2]. This activation process allows the polymer surface to become hydrophilic, in order to be well wet by an electrolessplating solution [3,4]. Gas-plasma treatment under various glow-discharge conditions was extensively used for this type of surface modification of fluoropolymers [5]. To deposit copper, it was proved that the treatment by N 2 , NH 3 or O 2 plasmas increased the reactivity of polymers [6][7][8]. Polar groups introduced by plasma treatment on the film surface favor the reaction of copper to form a copper-nitrogen-carbon complex in the interface region [9]. Different mixtures of N 2 and H 2 , which are more environmentally friendly and easier to handle in industry than ammonia, were studied in order to improve the adhesion of copper onto fluoropolymers. Low-temperature plasmas of nitrogen/hydrogen mixtures contain NH x gaseous precursors that can induce the formation of amino groups at the surface. For example, using a N 2 /H 2 plasma for treating polypropylene (PP) surface, a signifi-