When developing control systems, an important issue arises of choosing an operator, which forms the control function. The standard approach is to use a PI- or PID-controller, a more advanced approach involves ANNs training for this purpose. A comparative analysis of the PI- and neurocontroller performances makes it possible to establish the disadvantages and advantages of each of the compared controllers, which is an important scientific and applied problem. The purpose of the work was to conduct a comparative analysis of the performance of the PI-controller and the neurocontroller based on a set of evaluation indicators for plants of the second and third orders. Such a comparison was carried out by using an approach to the synthesis of both controllers, which involved the minimization of a complex objective function. The latter is obtained as a result of reducing the problem of optimal control with constraints to the problem of unconstrained optimization. The analysis showed that according to the settling time indicator (optimization criterion), the neurocontroller has an advantage of 6.1...96.2% for the modelled plants. At the same time, according to other indicators of the control quality, the PI-controller has an advantage. In addition, the synthesis of a neurocontroller in terms of finding the minimum of the objective function is a more difficult problem. For its solution, a bigger number of iterations of the VCT-PSO optimization algorithm is required. It is rationally to set more than 1000 iterations and swarm population in the range 30…50 particles. A comparative analysis by the settling time of the neurocontroller and PI-controller, which is tuned according to engineering methods, showed significant reserves for improving this indicator. Thus, if the requirements for settling time minimization are quite strict, then it is advisable to use a neurocontroller. The obtained results will make it possible to develop recommendations for the rational choice of the control operator when solving practical problems of the control systems synthesis